The effect of salt content on the structure of iota-carrageenan systems : (23)Na DQF NMR and rheological studies

Copyright (c) 2009 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 47(2009), 4 vom: 01. Apr., Seite 307-12
1. Verfasser: Gobet, Mallory (VerfasserIn)
Weitere Verfasser: Mouaddab, Mohamed, Cayot, Nathalie, Bonny, Jean-Marie, Guichard, Elisabeth, Le Quéré, Jean-Luc, Moreau, Céline, Foucat, Loïc
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Sodium Isotopes Sodium Chloride 451W47IQ8X Carrageenan 9000-07-1
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520 |a (23)Na NMR spectroscopy has been used to study the effects of Na(+) ion concentrations on the structure of 1% (w/w) iota-carrageenan systems, a natural gelling polysaccharide used as a thickener in the food industry. Rheological and (23)Na T(1) relaxation time measurements revealed that gel formation correlates with decreases in ion mobility over the range of 0-3% (w/w) sodium content. (23)Na single-quantum (SQ) and double-quantum-filtered (DQF) NMR experiments performed on these systems provided evidence for a 'bound' sodium ion fraction in a specifically ordered environment. These results have allowed us to propose a model for the carrageenan gelation mechanism in the presence of Na(+) ions 
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