Achieving Ultrahigh-Rate and High-Safety Li+ Storage Based on Interconnected Tunnel Structure in Micro-Size Niobium Tungsten Oxides

Achieving Ultrahigh-Rate and High-Safety Li+ Storage Based on Interconnected Tunnel Structure in Micro-Size Niobium Tungsten Oxides

© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 12 vom: 04. März, Seite e1905295
1. Verfasser: Yang, Yang (VerfasserIn)
Weitere Verfasser: Zhu, He, Xiao, Jinfei, Geng, Hongbo, Zhang, Yufei, Zhao, Jinbao, Li, Gen, Wang, Xun-Li, Li, Cheng Chao, Liu, Qi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article anode materials high-rate electrode materials high-safety lithium-ion batteries niobium tungsten oxides
Beschreibung
Zusammenfassung:© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Developing advanced high-rate electrode materials has been a crucial aspect for next-generation lithium ion batteries (LIBs). A conventional nanoarchitecturing strategy is suggested to improve the rate performance of materials but inevitably brings about compromise in volumetric energy density, cost, safety, and so on. Here, micro-size Nb14 W3 O44 is synthesized as a durable high-rate anode material based on a facile and scalable solution combustion method. Aberration-corrected scanning transmission electron microscopy reveals the existence of open and interconnected tunnels in the highly crystalline Nb14 W3 O44 , which ensures facile Li+ diffusion even within micro-size particles. In situ high-energy synchrotron XRD and XANES combined with Raman spectroscopy and computational simulations clearly reveal a single-phase solid-solution reaction with reversible cationic redox process occurring in the NWO framework due to the low-barrier Li+ intercalation. Therefore, the micro-size Nb14 W3 O44 exhibits durable and ultrahigh rate capability, i.e., ≈130 mAh g-1 at 10 C, after 4000 cycles. Most importantly, the micro-size Nb14 W3 O44 anode proves its highest practical applicability by the fabrication of a full cell incorporating with a high-safety LiFePO4 cathode. Such a battery shows a long calendar life of over 1000 cycles and an enhanced thermal stability, which is superior than the current commercial anodes such as Li4 Ti5 O12
Beschreibung:Date Revised 30.09.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201905295