Superstrong Lightweight Aerogel with Supercontinuous Layer by Surface Reaction

Superstrong Lightweight Aerogel with Supercontinuous Layer by Surface Reaction

© 2025 Wiley‐VCH GmbH.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - 37(2025), 10 vom: 03. März, Seite e2418083
Auteur principal: Zhou, Tianpei (Auteur)
Autres auteurs: He, Linbo, Zhen, Yu, Tai, Xiaolin, Dai, Shun, Wu, Kaijin, Ding, Honghe, Xia, Tianpu, Zhang, Xun, Cai, Xueru, Jiang, Fangzhou, Zhu, Zhiqiang, Huang, Fangsheng, Li, Chen, Li, Yaping, Zhu, Junfa, Chu, Wangsheng, Lin, Yue, Ni, Yong, Xie, Yi, Wu, Changzheng
Format: Article en ligne
Langue:English
Publié: 2025
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article aerogel supercontinuous layer superstrong and ultralight surface chemistry reaction thermal insulation
LEADER 01000caa a22002652c 4500
001 NLM383530865
003 DE-627
005 20250509063045.0
007 cr uuu---uuuuu
008 250507s2025 xx |||||o 00| ||eng c
024 7 |a 10.1002/adma.202418083  |2 doi 
028 5 2 |a pubmed25n1341.xml 
035 |a (DE-627)NLM383530865 
035 |a (NLM)39871760 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Zhou, Tianpei  |e verfasserin  |4 aut 
245 1 0 |a Superstrong Lightweight Aerogel with Supercontinuous Layer by Surface Reaction 
264 1 |c 2025 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Revised 12.03.2025 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a © 2025 Wiley‐VCH GmbH. 
520 |a Breaking the thermal, mechanical and lightweight performance limit of aerogels has pivotal significance on thermal protection, new energy utilization, high-temperature catalysis, structural engineering, and physics, but is severely limited by the serious discrete characteristics between grain boundary and nano-units interfaces. Herein, a thermodynamically driven surface reaction and confined crystallization process is reported to synthesize a centimeter-scale supercontinuous ZrO2 nanolayer on ZrO2-SiO2 fiber aerogel surface, which significantly improved its thermal and mechanical properties with density almost unchanged (≈26 mg cm-3). Systematic structure analysis confirms that the supercontinuous layer achieves a close connection between grains and fibers through Zr─O─Si bonds. The as-prepared aerogel exhibits record-breaking specific strength (≈84615 N m kg-1, can support up to ≈227 272 times aerogel mass) and dynamic impact resistance (withstanding impacts up to 500 times aerogel mass and up to 200 cycling stability at 80% strain). Besides, its temperature resistance has also been greatly optimized (400 °C enhancement, stability at 1500 °C). This work will provide a new perspective for exploring the limits of lightweight, high strength, and thermal properties of solid materials 
650 4 |a Journal Article 
650 4 |a aerogel 
650 4 |a supercontinuous layer 
650 4 |a superstrong and ultralight 
650 4 |a surface chemistry reaction 
650 4 |a thermal insulation 
700 1 |a He, Linbo  |e verfasserin  |4 aut 
700 1 |a Zhen, Yu  |e verfasserin  |4 aut 
700 1 |a Tai, Xiaolin  |e verfasserin  |4 aut 
700 1 |a Dai, Shun  |e verfasserin  |4 aut 
700 1 |a Wu, Kaijin  |e verfasserin  |4 aut 
700 1 |a Ding, Honghe  |e verfasserin  |4 aut 
700 1 |a Xia, Tianpu  |e verfasserin  |4 aut 
700 1 |a Zhang, Xun  |e verfasserin  |4 aut 
700 1 |a Cai, Xueru  |e verfasserin  |4 aut 
700 1 |a Jiang, Fangzhou  |e verfasserin  |4 aut 
700 1 |a Zhu, Zhiqiang  |e verfasserin  |4 aut 
700 1 |a Huang, Fangsheng  |e verfasserin  |4 aut 
700 1 |a Li, Chen  |e verfasserin  |4 aut 
700 1 |a Li, Yaping  |e verfasserin  |4 aut 
700 1 |a Zhu, Junfa  |e verfasserin  |4 aut 
700 1 |a Chu, Wangsheng  |e verfasserin  |4 aut 
700 1 |a Lin, Yue  |e verfasserin  |4 aut 
700 1 |a Ni, Yong  |e verfasserin  |4 aut 
700 1 |a Xie, Yi  |e verfasserin  |4 aut 
700 1 |a Wu, Changzheng  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Advanced materials (Deerfield Beach, Fla.)  |d 1998  |g 37(2025), 10 vom: 03. März, Seite e2418083  |w (DE-627)NLM098206397  |x 1521-4095  |7 nnas 
773 1 8 |g volume:37  |g year:2025  |g number:10  |g day:03  |g month:03  |g pages:e2418083 
856 4 0 |u http://dx.doi.org/10.1002/adma.202418083  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_350 
951 |a AR 
952 |d 37  |j 2025  |e 10  |b 03  |c 03  |h e2418083