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|a 10.2166/wst.2024.274
|2 doi
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|a pubmed24n1520.xml
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|a (DE-627)NLM377028495
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|a (NLM)39215728
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|a DE-627
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|a eng
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|a Wang, Rui
|e verfasserin
|4 aut
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|a The electrocatalytic degradation of 1,4-dioxane by Co-Bi/GAC particle electrode
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 31.08.2024
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|a Date Revised 31.08.2024
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a © 2024 The Authors This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY-NC-ND 4.0), which permits copying and redistribution for non-commercial purposes with no derivatives, provided the original work is properly cited (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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|a Efficient degradation of industrial organic wastewater has become a significant environmental concern. Electrochemical oxidation technology is promising due to its high catalytic degradation ability. In this study, Co-Bi/GAC particle electrodes were prepared and characterized for degradation of 1,4-dioxane. The electrochemical process parameters were optimized by response surface methodology (RSM), and the influence of water quality factors on the removal rate of 1,4-dioxane was investigated. The results showed that the main influencing factors were the Co/Bi mass ratio and calcination temperature. The carrier metals, Co and Bi, existed mainly on the GAC surface as Co3O4 and Bi2O3. The removal of 1,4-dioxane was predominantly achieved through the synergistic reaction of electrode adsorption, anodic oxidation, and particle electrode oxidation, with ·OH playing a significant role as the main active free radical. Furthermore, the particle electrode was demonstrated in different acid-base conditions (pH = 3, 5, 7, 9, and 11). However, high concentrations of Cl- and NO3- hindered the degradation process, potentially participating in competitive reactions. Despite this, the particle electrode exhibited good stability after five cycles. The results provide a new perspective for constructing efficient and stable three-dimensional (3D) electrocatalytic particle electrodes to remove complex industrial wastewater
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|a Journal Article
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|a 1
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|a 4-dioxane
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|a Co–Bi/GAC
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|a particle electrode
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|a response surface methodology
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|a three-dimensional electrocatalysis
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|a Dioxanes
|2 NLM
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|a 1,4-dioxane
|2 NLM
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|a J8A3S10O7S
|2 NLM
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|a Cobalt
|2 NLM
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|a 3G0H8C9362
|2 NLM
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|a Water Pollutants, Chemical
|2 NLM
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|a Bismuth
|2 NLM
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|a U015TT5I8H
|2 NLM
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|a Charcoal
|2 NLM
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|a 16291-96-6
|2 NLM
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1 |
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|a Dai, Zhineng
|e verfasserin
|4 aut
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|a Zhang, Wenqi
|e verfasserin
|4 aut
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|a Ma, Chao
|e verfasserin
|4 aut
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|i Enthalten in
|t Water science and technology : a journal of the International Association on Water Pollution Research
|d 1986
|g 90(2024), 4 vom: 31. Aug., Seite 1132-1148
|w (DE-627)NLM098149431
|x 0273-1223
|7 nnns
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|g volume:90
|g year:2024
|g number:4
|g day:31
|g month:08
|g pages:1132-1148
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|u http://dx.doi.org/10.2166/wst.2024.274
|3 Volltext
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