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240825s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202408547
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|a eng
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|a Wadhwa, Sagar
|e verfasserin
|4 aut
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|a Direct Chiral Discrimination with NMR
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|c 2024
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 24.08.2024
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|a published: Print-Electronic
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|a Citation Status Publisher
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|a © 2024 The Author(s). Advanced Materials published by Wiley‐VCH GmbH.
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|a Unaided nuclear magnetic resonance (NMR) spectroscopy is considered incapable of distinguishing enantiomers. However, as first derived by A.D. Buckingham, the tensor coupling the electric and magnetic dipoles is space-dependent, which varies according to the molecular structure, hence, would be different for two enantiomers. Exploiting the odd-parity coupling tensor, a new variant of a double-resonant radiofrequency (RF) NMR detector is developed, which is sensitive to both electric and magnetic dipoles. Using the detector, a new method for liquid-state NMR is developed and elaborated, with which two enantiomers are successfully discriminated
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|a Journal Article
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|a NMR
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|a chirality
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|a drug discovery
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|a enantiomeric excess
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|a Buyens, Dominique
|e verfasserin
|4 aut
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|a Korvink, Jan G
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2024) vom: 23. Aug., Seite e2408547
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