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240206s2024 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.3c02512
|2 doi
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|a eng
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|a Soni, Jitendra
|e verfasserin
|4 aut
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|a Recent Advancements in Understanding of Growth and Properties of Antiwear Tribofilms Derived from Zinc Dialkyl Dithiophosphate Additives under Nanoscale Sliding Contacts
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|c 2024
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 05.02.2024
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|a published: Print-Electronic
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|a Citation Status Publisher
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|a Zinc dialkyl dithiophosphate (ZDDP) is a key antiwear additive in lubricants that forms robust phosphate glass-based tribofilms to mitigate wear on rubbing surfaces. The quest to unravel the enigma of these antiwear film formations on sliding surfaces has persisted as an enduring mystery, despite nearly a century of fervent research. This paper presents a comprehensive review of nanotribological investigations, centering on the tribochemical decomposition of ZDDP antiwear additives. The core of the Review explores investigations conducted through the in situ AFM-based technique, which has been used to unveil the underlying stress-assisted thermal activation (SATA) mechanism behind the formation of antiwear tribofilms on diverse surfaces. A thorough analysis is presented, encompassing governing factors, such as compression, shear, and temperature, that wield influence over the intricate process of tribofilm formation. This is substantiated by a spectrum of structural and chemical characterization-based inferences. Furthermore, atomic-scale computer simulation studies are discussed that provide profound insights into tribochemical reaction mechanisms and elucidate the details of chemical processes at atomic level
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|a Journal Article
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|a Review
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|a Gosvami, Nitya Nand
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
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|u http://dx.doi.org/10.1021/acs.langmuir.3c02512
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