Boosting the Performances of Semitransparent Organic Photovoltaics via Synergetic Near-Infrared Light Management

Boosting the Performances of Semitransparent Organic Photovoltaics via Synergetic Near-Infrared Light Management

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 18 vom: 01. Mai, Seite e2311305
1. Verfasser: Xu, Tao (VerfasserIn)
Weitere Verfasser: Deng, Baozhong, Zheng, Kaiwen, Li, Hongyu, Wang, Zihan, Zhong, Yunbo, Zhang, Chengxi, Lévêque, Gaëtan, Grandidier, Bruno, Bachelot, Renaud, Treguer-Delapierre, Mona, Qi, Yabing, Wang, Shenghao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article high‐throughput optical screening near‐infrared absorption enhancement optical engineering plasmonics semitransparent organic photovoltaics
Beschreibung
Zusammenfassung:© 2024 Wiley‐VCH GmbH.
Semitransparent organic photovoltaics (ST-OPVs) offer promising prospects for application in building-integrated photovoltaic systems and greenhouses, but further improvement of their performance faces a delicate trade-off between the two competing indexes of power conversion efficiency (PCE) and average visible transmittance (AVT). Herein, the authors take advantage of coupling plasmonics with the optical design of ST-OPVs to enhance near-infrared absorption and hence simultaneously improve efficiency and visible transparency to the maximum extent. By integrating core-bishell PdCuAu@SiO2 nanotripods that act as optically isotropic Lambertian sources with near-infrared-customized localized surface plasmon resonance in an optimal ternary PM6:BTP-eC9:L8-BO-based ST-OPV, it is shown that their interplay with a multilayer optical coupling layer, consisting of ZnS(130 nm)/Na3AlF6(60 nm)/WO3(100 nm)/LaF3(50 nm) identified from high-throughput optical screening, leads to a record-high PCE of 16.14% (certified as 15.90%) along with an excellent AVT of 33.02%. The strong enhancement of the light utilization efficiency by ≈50% as compared to the counterpart device without optical engineering provides an encouraging and universal pathway for promoting breakthroughs in ST-OPVs from meticulous optical design
Beschreibung:Date Revised 02.05.2024
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.202311305