Enhanced dewatering extent of sludge by Fe3O4-driven heterogeneous Fenton
Copyright © 2023 Elsevier Ltd. All rights reserved.
| Veröffentlicht in: | Waste management (New York, N.Y.). - 1999. - 174(2024) vom: 15. Jan., Seite 666-673 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2024
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| Zugriff auf das übergeordnete Werk: | Waste management (New York, N.Y.) |
| Schlagworte: | Journal Article Fe(3)O(4) Heterogeneous Fenton Improvement mechanism Sludge dewatering Sewage Hydrogen Peroxide BBX060AN9V Iron E1UOL152H7 mehr... |
| Zusammenfassung: | Copyright © 2023 Elsevier Ltd. All rights reserved. Homogeneous Fenton (Fe2+/H2O2) serves as a high-efficiency conditioning method for sludge dewatering due to the generation of strong oxidizing hydroxyl radicals (OH). However, high dose of ferric salts produces iron-rich dewatered sludge and decrease sludge organic matters, which will not be conducive to the subsequent disposal and reutilization. Considering advantages of Fe3O4 as heterogeneous Fenton catalyst, Fe3O4-activated H2O2 (Fe3O4 + H2O2) in this study was adopted to improve sludge deep-dewatering. Reduction efficiency of the bound water (71.3 %) after Fe3O4 + H2O2 treatment (after a reaction time of 30 min) were much higher than those in the Fe2++H2O2 treatment. Especially, the moisture content of treated sludge cake by Fe3O4 + H2O2 remarkably decreased from 86.4 % to 61.3 %. Improvement mechanism of sludge dewatering after Fe3O4 + H2O2 treatment mainly included electrostatic neutralization, reactive radical oxidation, and skeleton building by analysis of contribution factors. The generation of H+ in acidification could neutralize the negatively charged compounds to promote sludge hydrophobicity. Meanwhile reactive radicals generated from Fe3O4 + H2O2 destroyed sludge extracellular polymeric substances and cell structure to release intracellular water. Furthermore, Fe3O4 as a skeleton builder could reconstruct destructive sludge flocs and form new dewatering channels. Finally, low Fe leaching content and recoverability of Fe3O4 effectively will decrease environmental implication |
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| Beschreibung: | Date Completed 16.01.2024 Date Revised 16.01.2024 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1879-2456 |
| DOI: | 10.1016/j.wasman.2023.12.044 |