|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM36480551X |
| 003 |
DE-627 |
| 005 |
20240201232019.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231226s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202307645
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1277.xml
|
| 035 |
|
|
|a (DE-627)NLM36480551X
|
| 035 |
|
|
|a (NLM)37989269
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Liu, Haoxuan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Multifunctional Separator Enables High-Performance Sodium Metal Batteries in Carbonate-Based Electrolytes
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 01.02.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
|
| 520 |
|
|
|a Sodium metal has become one of the most promising anodes for next-generation cheap and high-energy-density metal batteries; however, challenges caused by the uncontrollable sodium dendrite growth and fragile solid electrolyte interphase (SEI) restrict their large-scale practical applications in low-cost and wide-voltage-window carbonate electrolytes. Herein, a novel multifunctional separator with lightweight and high thinness is proposed, assembled by the cobalt-based metal-organic framework nanowires (Co-NWS), to replace the widely applied thick and heavy glass fiber separator. Benefitting from its abundant sodiophilic functional groups and densely stacked nanowires, Co-NWS not only exhibits outstanding electrolyte wettability and effectively induces uniform Na+ ion flux as a strong ion redistributor but also favors constructing the robust N,F-rich SEI layer. Satisfactorily, with 10 µL carbonate electrolyte, a Na|Co-NWS|Cu half-cell delivers stable cycling (over 260 cycles) with a high average Coulombic efficiency of 98%, and the symmetric cell shows a long cycle life of more than 500 h. Remarkably, the full cell shows a long-term life span (over 1500 cycles with 92% capacity retention) at high current density in the carbonate electrolyte. This work opens up a strategy for developing dendrite-free, low-cost, and long-life-span sodium metal batteries in carbonate-based electrolytes
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a carbonate electrolytes
|
| 650 |
|
4 |
|a metal-organic frameworks nanowires
|
| 650 |
|
4 |
|a separators
|
| 650 |
|
4 |
|a sodium metal batteries
|
| 700 |
1 |
|
|a Zheng, Xiaoyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Du, Yumeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Borrás, Marcela Chaki
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Kuan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Konstantinov, Konstantin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Pang, Wei Kong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chou, Shulei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Huakun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Dou, Shixue
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Chao
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 5 vom: 29. Feb., Seite e2307645
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:5
|g day:29
|g month:02
|g pages:e2307645
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202307645
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 5
|b 29
|c 02
|h e2307645
|