High-Sulfur Loading and Single Ion-Selective Membranes for High-Energy and Durable Decoupled Aqueous Batteries
© 2023 Wiley-VCH GmbH.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 3 vom: 01. Jan., Seite e2307298 |
---|---|
1. Verfasser: | |
Weitere Verfasser: | , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2024
|
Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article Zn-S aqueous batteries decoupled batteries high sulfur loading ion channels ion-selective membranes |
Zusammenfassung: | © 2023 Wiley-VCH GmbH. The decoupled battery design is promising for breaking the energy density limit of traditional aqueous batteries. However, the complex battery configuration and low-selective separator membranes restrict their energy output and service time. Herein, a zinc-sulfur decoupled aqueous battery is achieved by designing a high-mass loading sulfur electrode and single ion-selective membrane (ISM). A vertically assembled nanosheet network constructed with the assistance of a magnetic field enables facile electron and ion conduction in thick sulfur electrodes, which is conducive to boosting the cell-level energy output. For the tailored ISM, the Na ions anchored on its skeleton effectively prevent the crossover of OH- or Cu2+ , facilitating the transport of Na+ and ensuring structural and mechanical stability. Consequently, the Zn-S aqueous battery achieves a reversible energy density of 3988 Wh kgs -1 (by sulfur mass), stable operation over 300 cycles, and an energy density of 53.2 mWh cm-2 . The sulfur-based decoupled system may be of immediate benefit toward safe, reliable, and affordable static energy storage |
---|---|
Beschreibung: | Date Revised 18.01.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.202307298 |