Controlled Growth of Single-Crystal Graphene Wafers on Twin-Boundary-Free Cu(111) Substrates

© 2023 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 17 vom: 01. Apr., Seite e2308802
1. Verfasser: Zhu, Yeshu (VerfasserIn)
Weitere Verfasser: Zhang, Jincan, Cheng, Ting, Tang, Jilin, Duan, Hongwei, Hu, Zhaoning, Shao, Jiaxin, Wang, Shiwei, Wei, Mingyue, Wu, Haotian, Li, Ang, Li, Sheng, Balci, Osman, Shinde, Sachin M, Ramezani, Hamideh, Wang, Luda, Lin, Li, Ferrari, Andrea C, Yakobson, Boris I, Peng, Hailin, Jia, Kaicheng, Liu, Zhongfan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article CVD graphene graphene wafer single‐crystal Cu(111)
LEADER 01000caa a22002652 4500
001 NLM36370597X
003 DE-627
005 20240425232433.0
007 cr uuu---uuuuu
008 231226s2024 xx |||||o 00| ||eng c
024 7 |a 10.1002/adma.202308802  |2 doi 
028 5 2 |a pubmed24n1386.xml 
035 |a (DE-627)NLM36370597X 
035 |a (NLM)37878366 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Zhu, Yeshu  |e verfasserin  |4 aut 
245 1 0 |a Controlled Growth of Single-Crystal Graphene Wafers on Twin-Boundary-Free Cu(111) Substrates 
264 1 |c 2024 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Revised 25.04.2024 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a © 2023 Wiley‐VCH GmbH. 
520 |a Single-crystal graphene (SCG) wafers are needed to enable mass-electronics and optoelectronics owing to their excellent properties and compatibility with silicon-based technology. Controlled synthesis of high-quality SCG wafers can be done exploiting single-crystal Cu(111) substrates as epitaxial growth substrates recently. However, current Cu(111) films prepared by magnetron sputtering on single-crystal sapphire wafers still suffer from in-plane twin boundaries, which degrade the SCG chemical vapor deposition. Here, it is shown how to eliminate twin boundaries on Cu and achieve 4 in. Cu(111) wafers with ≈95% crystallinity. The introduction of a temperature gradient on Cu films with designed texture during annealing drives abnormal grain growth across the whole Cu wafer. In-plane twin boundaries are eliminated via migration of out-of-plane grain boundaries. SCG wafers grown on the resulting single-crystal Cu(111) substrates exhibit improved crystallinity with >97% aligned graphene domains. As-synthesized SCG wafers exhibit an average carrier mobility up to 7284 cm2 V-1 s-1 at room temperature from 103 devices and a uniform sheet resistance with only 5% deviation in 4 in. region 
650 4 |a Journal Article 
650 4 |a CVD graphene 
650 4 |a graphene wafer 
650 4 |a single‐crystal Cu(111) 
700 1 |a Zhang, Jincan  |e verfasserin  |4 aut 
700 1 |a Cheng, Ting  |e verfasserin  |4 aut 
700 1 |a Tang, Jilin  |e verfasserin  |4 aut 
700 1 |a Duan, Hongwei  |e verfasserin  |4 aut 
700 1 |a Hu, Zhaoning  |e verfasserin  |4 aut 
700 1 |a Shao, Jiaxin  |e verfasserin  |4 aut 
700 1 |a Wang, Shiwei  |e verfasserin  |4 aut 
700 1 |a Wei, Mingyue  |e verfasserin  |4 aut 
700 1 |a Wu, Haotian  |e verfasserin  |4 aut 
700 1 |a Li, Ang  |e verfasserin  |4 aut 
700 1 |a Li, Sheng  |e verfasserin  |4 aut 
700 1 |a Balci, Osman  |e verfasserin  |4 aut 
700 1 |a Shinde, Sachin M  |e verfasserin  |4 aut 
700 1 |a Ramezani, Hamideh  |e verfasserin  |4 aut 
700 1 |a Wang, Luda  |e verfasserin  |4 aut 
700 1 |a Lin, Li  |e verfasserin  |4 aut 
700 1 |a Ferrari, Andrea C  |e verfasserin  |4 aut 
700 1 |a Yakobson, Boris I  |e verfasserin  |4 aut 
700 1 |a Peng, Hailin  |e verfasserin  |4 aut 
700 1 |a Jia, Kaicheng  |e verfasserin  |4 aut 
700 1 |a Liu, Zhongfan  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Advanced materials (Deerfield Beach, Fla.)  |d 1998  |g 36(2024), 17 vom: 01. Apr., Seite e2308802  |w (DE-627)NLM098206397  |x 1521-4095  |7 nnns 
773 1 8 |g volume:36  |g year:2024  |g number:17  |g day:01  |g month:04  |g pages:e2308802 
856 4 0 |u http://dx.doi.org/10.1002/adma.202308802  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_350 
951 |a AR 
952 |d 36  |j 2024  |e 17  |b 01  |c 04  |h e2308802