Anion-Incorporated Mg-Ion Solvation Modulation Enables Fast Magnesium Storage Kinetics of Conversion-Type Cathode Materials
© 2023 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 19 vom: 24. Mai, Seite e2208289 |
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| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article anion modulation cathode materials copper selenide rechargeable magnesium batteries solvation structure |
| Zusammenfassung: | © 2023 Wiley-VCH GmbH. Rechargeable magnesium batteries (RMB) have emerged as one of the most promising alternatives to lithium-ion batteries due to the prominent advantages of magnesium metal anodes. Nevertheless, their application is hindered by sluggish Mg-ion storage kinetics in cathodes, although various structural modifications of cathode materials have been performed. Herein, an electrolyte design using an anion-incorporated Mg-ion solvation structure is developed to promote the Mg-ion storage reactions of conversion-type cathode materials. The addition of the trifluoromethanesulfonate anion (OTf- ) in the ether-based Mg-ion electrolyte modulates the solvation structure of Mg2+ from [Mg(DME)3 ]2+ to [Mg(DME)2.5 OTf]+ (DME = dimethoxy ethane), which facilitates Mg-ion desolvation and thus significantly expedites the charge transfer of the cathode material. As a result, the as-prepared CuSe cathode material on copper current collector exhibits a considerable increase in magnesium storage capacity from 61% (228 mAh g-1 ) to 95% (357 mAh g-1 ) of the theoretical capacity at 0.1 A g-1 and a more than twofold capacity increase at a high current density of 1.0 A g-1 . This work provides an efficient strategy via electrolyte modulation to achieve high-rate conversion-type cathode materials for RMBs. The incorporation of the trifluoromethanesulfonate anion in the Mg-ion solvation structure of the borate-based Mg-ion electrolyte enables the fast magnesium storage kinetics of the conversion-type cathode materials. The as-prepared copper selenide cathode achieved a more than twofold capacity increase at a high rate and the highest reversible capacities compared to those of the previously reported metal selenide cathodes |
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| Beschreibung: | Date Completed 11.05.2023 Date Revised 11.05.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202208289 |