Modified UiO-66-Br Microphotocatalyst with High Electron Mobility Enhances Tetracycline Degradation

In this work, the Br functional group on the ligand UiO-66-Br was modified with a Bi-O bond through the secondary solvothermal method, and the synthesis method of visible light catalyst UB (UiO-66-BiOBr) with high electron mobility was explored. The findings indicate that the effective charge transf...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 10 vom: 14. März, Seite 3678-3691
1. Verfasser: Wei, Lihong (VerfasserIn)
Weitere Verfasser: Zhang, Yao, Jiang, Jinyuan, Yang, Yinbo, Liu, Hui
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a In this work, the Br functional group on the ligand UiO-66-Br was modified with a Bi-O bond through the secondary solvothermal method, and the synthesis method of visible light catalyst UB (UiO-66-BiOBr) with high electron mobility was explored. The findings indicate that the effective charge transfer of the functional group-modified material UB is 2.98 times and 1.22 times that of BiOBr and traditional UiO-66/BiOBr heterojunctions, respectively. Under simulated sunlight irradiation, the removal rate of tetracycline can reach 88.71%, and the photocatalytic performance is 22.73 times higher than that of UiO-66-Br. Moreover, it maintains good adsorption and photocatalytic performance under different laboratory and actual engineering water environment conditions. In the complex water environment of municipal wastewater, the degradation effect reaches more than 80%. Finally, the decomposition pathways of TC and ecotoxicities of the intermediates were analyzed via combining theoretical calculation, LC-MS/MS, and T.E.S.T 
650 4 |a Journal Article 
700 1 |a Zhang, Yao  |e verfasserin  |4 aut 
700 1 |a Jiang, Jinyuan  |e verfasserin  |4 aut 
700 1 |a Yang, Yinbo  |e verfasserin  |4 aut 
700 1 |a Liu, Hui  |e verfasserin  |4 aut 
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