Modified UiO-66-Br Microphotocatalyst with High Electron Mobility Enhances Tetracycline Degradation
In this work, the Br functional group on the ligand UiO-66-Br was modified with a Bi-O bond through the secondary solvothermal method, and the synthesis method of visible light catalyst UB (UiO-66-BiOBr) with high electron mobility was explored. The findings indicate that the effective charge transf...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 10 vom: 14. März, Seite 3678-3691 |
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| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2023
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | In this work, the Br functional group on the ligand UiO-66-Br was modified with a Bi-O bond through the secondary solvothermal method, and the synthesis method of visible light catalyst UB (UiO-66-BiOBr) with high electron mobility was explored. The findings indicate that the effective charge transfer of the functional group-modified material UB is 2.98 times and 1.22 times that of BiOBr and traditional UiO-66/BiOBr heterojunctions, respectively. Under simulated sunlight irradiation, the removal rate of tetracycline can reach 88.71%, and the photocatalytic performance is 22.73 times higher than that of UiO-66-Br. Moreover, it maintains good adsorption and photocatalytic performance under different laboratory and actual engineering water environment conditions. In the complex water environment of municipal wastewater, the degradation effect reaches more than 80%. Finally, the decomposition pathways of TC and ecotoxicities of the intermediates were analyzed via combining theoretical calculation, LC-MS/MS, and T.E.S.T |
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| Beschreibung: | Date Completed 14.03.2023 Date Revised 14.03.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.2c03308 |