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231226s2023 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.2c03278
|2 doi
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|a pubmed24n1175.xml
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|a (NLM)36757158
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Yuan, Liang
|e verfasserin
|4 aut
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|a Flexible Azo-Polyimide-Based Smart Surface with Photoregulatable Surface Micropatterns
|b Toward Rewritable Information Storage and Wrinkle-Free Device Fabrication
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|c 2023
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 22.02.2023
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|a Date Revised 22.02.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Stimulus-sensitive materials are of great fascination in surface and interface science owing to their dynamically tunable surface properties and/or morphologies. Herein, we have synthesized an azobenzene-containing polyimide (azo-PI) with enhanced chain flexibility for the fabrication of photosensitive surface patterns on a film/substrate wrinkle system or wrinkle-free devices. The phototriggered cis-trans isomerization kinetics of azobenzene groups in the novel azo-PI with various chain structures were systematically investigated. On the basis of the characteristics of stress relaxation that azobenzene reversible cis-trans isomerization induces in the wrinkled azo-PI film/substrate system, a variety of rewritable visual surface patterns with high resolution and a long legibility time (>30 days) could be easily constructed via visible-light irradiation, enabling the wrinkled azo-PI surfaces to be used as rewritable information storage media. Meanwhile, because of the visible-light irradiation strategy, these photoresponsive surfaces could find potential application in the fabrication of wrinkle-free flexible devices. This study not only sheds light on the influence of the azo-polymer chain structure on its photoresponsive behavior but also provides a versatile strategy for realizing tailor-made smart surface patterns on multilayer functional devices
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|a Journal Article
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|a Chen, Jian
|e verfasserin
|4 aut
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|a Li, Yuxin
|e verfasserin
|4 aut
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|a Luo, Guangzeng
|e verfasserin
|4 aut
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|a Gao, Zhilu
|e verfasserin
|4 aut
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|a Zhou, Chunhua
|e verfasserin
|4 aut
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|a Li, Hui
|e verfasserin
|4 aut
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|a Xu, Peiming
|e verfasserin
|4 aut
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|a Zong, Chuanyong
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 39(2023), 7 vom: 21. Feb., Seite 2787-2796
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:39
|g year:2023
|g number:7
|g day:21
|g month:02
|g pages:2787-2796
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|u http://dx.doi.org/10.1021/acs.langmuir.2c03278
|3 Volltext
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