Flexible Azo-Polyimide-Based Smart Surface with Photoregulatable Surface Micropatterns : Toward Rewritable Information Storage and Wrinkle-Free Device Fabrication

Stimulus-sensitive materials are of great fascination in surface and interface science owing to their dynamically tunable surface properties and/or morphologies. Herein, we have synthesized an azobenzene-containing polyimide (azo-PI) with enhanced chain flexibility for the fabrication of photosensit...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 39(2023), 7 vom: 21. Feb., Seite 2787-2796
1. Verfasser: Yuan, Liang (VerfasserIn)
Weitere Verfasser: Chen, Jian, Li, Yuxin, Luo, Guangzeng, Gao, Zhilu, Zhou, Chunhua, Li, Hui, Xu, Peiming, Zong, Chuanyong
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM352669969
003 DE-627
005 20231226054246.0
007 cr uuu---uuuuu
008 231226s2023 xx |||||o 00| ||eng c
024 7 |a 10.1021/acs.langmuir.2c03278  |2 doi 
028 5 2 |a pubmed24n1175.xml 
035 |a (DE-627)NLM352669969 
035 |a (NLM)36757158 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Yuan, Liang  |e verfasserin  |4 aut 
245 1 0 |a Flexible Azo-Polyimide-Based Smart Surface with Photoregulatable Surface Micropatterns  |b Toward Rewritable Information Storage and Wrinkle-Free Device Fabrication 
264 1 |c 2023 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 22.02.2023 
500 |a Date Revised 22.02.2023 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Stimulus-sensitive materials are of great fascination in surface and interface science owing to their dynamically tunable surface properties and/or morphologies. Herein, we have synthesized an azobenzene-containing polyimide (azo-PI) with enhanced chain flexibility for the fabrication of photosensitive surface patterns on a film/substrate wrinkle system or wrinkle-free devices. The phototriggered cis-trans isomerization kinetics of azobenzene groups in the novel azo-PI with various chain structures were systematically investigated. On the basis of the characteristics of stress relaxation that azobenzene reversible cis-trans isomerization induces in the wrinkled azo-PI film/substrate system, a variety of rewritable visual surface patterns with high resolution and a long legibility time (>30 days) could be easily constructed via visible-light irradiation, enabling the wrinkled azo-PI surfaces to be used as rewritable information storage media. Meanwhile, because of the visible-light irradiation strategy, these photoresponsive surfaces could find potential application in the fabrication of wrinkle-free flexible devices. This study not only sheds light on the influence of the azo-polymer chain structure on its photoresponsive behavior but also provides a versatile strategy for realizing tailor-made smart surface patterns on multilayer functional devices 
650 4 |a Journal Article 
700 1 |a Chen, Jian  |e verfasserin  |4 aut 
700 1 |a Li, Yuxin  |e verfasserin  |4 aut 
700 1 |a Luo, Guangzeng  |e verfasserin  |4 aut 
700 1 |a Gao, Zhilu  |e verfasserin  |4 aut 
700 1 |a Zhou, Chunhua  |e verfasserin  |4 aut 
700 1 |a Li, Hui  |e verfasserin  |4 aut 
700 1 |a Xu, Peiming  |e verfasserin  |4 aut 
700 1 |a Zong, Chuanyong  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 39(2023), 7 vom: 21. Feb., Seite 2787-2796  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:39  |g year:2023  |g number:7  |g day:21  |g month:02  |g pages:2787-2796 
856 4 0 |u http://dx.doi.org/10.1021/acs.langmuir.2c03278  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 39  |j 2023  |e 7  |b 21  |c 02  |h 2787-2796