Manipulating Charge-Transfer Kinetics of Lithium-Rich Layered Oxide Cathodes in Halide All-Solid-State Batteries

Manipulating Charge-Transfer Kinetics of Lithium-Rich Layered Oxide Cathodes in Halide All-Solid-State Batteries

© 2022 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 5 vom: 03. Feb., Seite e2207234
1. Verfasser: Yu, Ruizhi (VerfasserIn)
Weitere Verfasser: Wang, Changhong, Duan, Hui, Jiang, Ming, Zhang, Anbang, Fraser, Adam, Zuo, Jiaxuan, Wu, Yanlong, Sun, Yipeng, Zhao, Yang, Liang, Jianwen, Fu, Jiamin, Deng, Sixu, Ren, Zhimin, Li, Guohua, Huang, Huan, Li, Ruying, Chen, Ning, Wang, Jiantao, Li, Xifei, Singh, Chandra Veer, Sun, Xueliang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article all-solid-state batteries charge-transfer kinetics lithium-rich layered oxide oxygen redox solid-state halide electrolyte
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520 |a Employing lithium-rich layered oxide (LLO) as the cathode of all-solid-state batteries (ASSBs) is highly desired for realizing high energy density. However, the poor kinetics of LLO, caused by its low electronic conductivity and significant oxygen-redox-induced structural degradation, has impeded its application in ASSBs. Here, the charge transfer kinetics of LLO is enhanced by constructing high-efficiency electron transport networks within solid-state electrodes, which considerably minimizes electron transfer resistance. In addition, an infusion-plus-coating strategy is introduced to stabilize the lattice oxygen of LLO, successfully suppressing the interfacial oxidation of solid electrolyte (Li3 InCl6 ) and structural degradation of LLO. As a result, LLO-based ASSBs exhibit a high discharge capacity of 230.7 mAh g-1 at 0.1 C and ultra-long cycle stability over 400 cycles. This work provides an in-depth understanding of the kinetics of LLO in solid-state electrodes, and affords a practically feasible strategy to obtain high-energy-density ASSBs 
650 4 |a Journal Article 
650 4 |a all-solid-state batteries 
650 4 |a charge-transfer kinetics 
650 4 |a lithium-rich layered oxide 
650 4 |a oxygen redox 
650 4 |a solid-state halide electrolyte 
700 1 |a Wang, Changhong  |e verfasserin  |4 aut 
700 1 |a Duan, Hui  |e verfasserin  |4 aut 
700 1 |a Jiang, Ming  |e verfasserin  |4 aut 
700 1 |a Zhang, Anbang  |e verfasserin  |4 aut 
700 1 |a Fraser, Adam  |e verfasserin  |4 aut 
700 1 |a Zuo, Jiaxuan  |e verfasserin  |4 aut 
700 1 |a Wu, Yanlong  |e verfasserin  |4 aut 
700 1 |a Sun, Yipeng  |e verfasserin  |4 aut 
700 1 |a Zhao, Yang  |e verfasserin  |4 aut 
700 1 |a Liang, Jianwen  |e verfasserin  |4 aut 
700 1 |a Fu, Jiamin  |e verfasserin  |4 aut 
700 1 |a Deng, Sixu  |e verfasserin  |4 aut 
700 1 |a Ren, Zhimin  |e verfasserin  |4 aut 
700 1 |a Li, Guohua  |e verfasserin  |4 aut 
700 1 |a Huang, Huan  |e verfasserin  |4 aut 
700 1 |a Li, Ruying  |e verfasserin  |4 aut 
700 1 |a Chen, Ning  |e verfasserin  |4 aut 
700 1 |a Wang, Jiantao  |e verfasserin  |4 aut 
700 1 |a Li, Xifei  |e verfasserin  |4 aut 
700 1 |a Singh, Chandra Veer  |e verfasserin  |4 aut 
700 1 |a Sun, Xueliang  |e verfasserin  |4 aut 
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773 1 8 |g volume:35  |g year:2023  |g number:5  |g day:03  |g month:02  |g pages:e2207234 
856 4 0 |u http://dx.doi.org/10.1002/adma.202207234  |3 Volltext 
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