Manipulating Charge-Transfer Kinetics of Lithium-Rich Layered Oxide Cathodes in Halide All-Solid-State Batteries

Bibliographische Detailangaben
Veröffentlicht in:	Advanced materials (Deerfield Beach, Fla.). - 1998. - 35(2023), 5 vom: 03. Feb., Seite e2207234
1. Verfasser:	Yu, Ruizhi (VerfasserIn)
Weitere Verfasser:	Wang, Changhong, Duan, Hui, Jiang, Ming, Zhang, Anbang, Fraser, Adam, Zuo, Jiaxuan, Wu, Yanlong, Sun, Yipeng, Zhao, Yang, Liang, Jianwen, Fu, Jiamin, Deng, Sixu, Ren, Zhimin, Li, Guohua, Huang, Huan, Li, Ruying, Chen, Ning, Wang, Jiantao, Li, Xifei, Singh, Chandra Veer, Sun, Xueliang
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2023
Zugriff auf das übergeordnete Werk:	Advanced materials (Deerfield Beach, Fla.)
Schlagworte:	Journal Article all-solid-state batteries charge-transfer kinetics lithium-rich layered oxide oxygen redox solid-state halide electrolyte

Beschreibung
Zusammenfassung:	© 2022 Wiley-VCH GmbH. Employing lithium-rich layered oxide (LLO) as the cathode of all-solid-state batteries (ASSBs) is highly desired for realizing high energy density. However, the poor kinetics of LLO, caused by its low electronic conductivity and significant oxygen-redox-induced structural degradation, has impeded its application in ASSBs. Here, the charge transfer kinetics of LLO is enhanced by constructing high-efficiency electron transport networks within solid-state electrodes, which considerably minimizes electron transfer resistance. In addition, an infusion-plus-coating strategy is introduced to stabilize the lattice oxygen of LLO, successfully suppressing the interfacial oxidation of solid electrolyte (Li3 InCl6 ) and structural degradation of LLO. As a result, LLO-based ASSBs exhibit a high discharge capacity of 230.7 mAh g-1 at 0.1 C and ultra-long cycle stability over 400 cycles. This work provides an in-depth understanding of the kinetics of LLO in solid-state electrodes, and affords a practically feasible strategy to obtain high-energy-density ASSBs
Beschreibung:	Date Completed 03.02.2023 Date Revised 03.02.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE
ISSN:	1521-4095
DOI:	10.1002/adma.202207234