Locally Concentrated Ionic Liquid Electrolyte with Partially Solvating Diluent for Lithium/Sulfurized Polyacrylonitrile Batteries
© 2022 The Authors. Advanced Materials published by Wiley-VCH GmbH.
| Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 49 vom: 27. Dez., Seite e2207155 |
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| Auteur principal: | |
| Autres auteurs: | , , , , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2022
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| Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
| Sujets: | Journal Article ionic liquids lithium-metal anodes locally concentrated electrolytes sulfurized polyacrylonitrile |
| Résumé: | © 2022 The Authors. Advanced Materials published by Wiley-VCH GmbH. The development of Li/sulfurized polyacrylonitrile (SPAN) batteries requires electrolytes that can form stable electrolyte/electrode interphases simultaneously on lithium-metal anodes (LMAs) and SPAN cathodes. Herein, a low-flammability locally concentrated ionic liquid electrolyte (LCILE) employing monofluorobenzene (mFBn) as the diluent is proposed for Li/SPAN cells. Unlike non-solvating diluents in other LCILEs, mFBn partially solvates Li+ , decreasing the coordination between Li+ and bis(fluorosulfonyl)imide (FSI- ). In turn, this triggers a more substantial decomposition of FSI- and consequently results in the formation of a solid electrolyte interphase (SEI) rich in inorganic compounds, which enables a remarkable Coulombic efficiency (99.72%) of LMAs. Meanwhile, a protective cathode electrolyte interphase (CEI), derived mainly from FSI- and organic cations, is generated on the SPAN cathodes, preventing the dissolution of polysulfides. Benefiting from the robust interphases simultaneously formed on both the electrodes, a highly stable cycling of Li/SPAN cells for 250 cycles with a capacity retention of 71% is achieved employing the LCILE and only 80% lithium-metal excess |
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| Description: | Date Completed 09.12.2022 Date Revised 09.12.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202207155 |