Enhanced dewaterability of sludge by Fe(II)-sludge biochar activate persulfate

Sludge biochar supported Fe(II) (Fe(II)-SBC) was successfully prepared using waste activated sludge as peroxydisulfate (PDS) activator to condition sludge for deep dewatering. The experimental results showed that Fe(II)-SBC with FeO on it could effectively active PDS to produce SO4-⋅ and HO⋅. The ra...

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Veröffentlicht in:Environmental technology. - 1993. - 45(2024), 5 vom: 15. Jan., Seite 854-866
1. Verfasser: Zhang, Yanping (VerfasserIn)
Weitere Verfasser: Pei, Jiahua, Zheng, Songchao, Li, Yibing, Lv, Ning, Ma, Liran
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Fe(II)-SBC persulfate skeleton builder sludge biochar sludge dewatering Sewage biochar Water 059QF0KO0R mehr... Ferrous Compounds Charcoal 16291-96-6
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520 |a Sludge biochar supported Fe(II) (Fe(II)-SBC) was successfully prepared using waste activated sludge as peroxydisulfate (PDS) activator to condition sludge for deep dewatering. The experimental results showed that Fe(II)-SBC with FeO on it could effectively active PDS to produce SO4-⋅ and HO⋅. The radicals could destroy the structure of sludge cells and extracellular polymeric substance (EPS), transformed the hydrophilic and tightly bound EPS into soluble-EPS, degrade partial proteins and polysaccharides and released bound water. The negatively charged groups on sludge floc were dripped off by SO4-⋅/HO⋅ or neutralized with Fe2+, Fe3+, H+, or Fe(II)-SBC, leading to an increase in zeta potential to -2.24 mV and sludge destabilization. The residual Fe(II)-SBC served as a skeleton builder that decreased the compression coefficient of the sludge cake to 0.75. Under the combined functions, the CST and SRF were reduced by 70% and 82.7%, respectively, and Wc was reduced to 72.4%. The byproducts of Fe3+ and SO42- finally remained in sludge cake in the form of NaFeSi2O6 and CaSO4 
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650 7 |a 059QF0KO0R  |2 NLM 
650 7 |a Ferrous Compounds  |2 NLM 
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700 1 |a Pei, Jiahua  |e verfasserin  |4 aut 
700 1 |a Zheng, Songchao  |e verfasserin  |4 aut 
700 1 |a Li, Yibing  |e verfasserin  |4 aut 
700 1 |a Lv, Ning  |e verfasserin  |4 aut 
700 1 |a Ma, Liran  |e verfasserin  |4 aut 
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773 1 8 |g volume:45  |g year:2024  |g number:5  |g day:15  |g month:01  |g pages:854-866 
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