Enhanced dewaterability of sludge by Fe(II)-sludge biochar activate persulfate
Sludge biochar supported Fe(II) (Fe(II)-SBC) was successfully prepared using waste activated sludge as peroxydisulfate (PDS) activator to condition sludge for deep dewatering. The experimental results showed that Fe(II)-SBC with FeO on it could effectively active PDS to produce SO4-⋅ and HO⋅. The ra...
| Veröffentlicht in: | Environmental technology. - 1993. - 45(2024), 5 vom: 15. Jan., Seite 854-866 |
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| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2024
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| Zugriff auf das übergeordnete Werk: | Environmental technology |
| Schlagworte: | Journal Article Fe(II)-SBC persulfate skeleton builder sludge biochar sludge dewatering Sewage biochar Water 059QF0KO0R mehr... |
| Zusammenfassung: | Sludge biochar supported Fe(II) (Fe(II)-SBC) was successfully prepared using waste activated sludge as peroxydisulfate (PDS) activator to condition sludge for deep dewatering. The experimental results showed that Fe(II)-SBC with FeO on it could effectively active PDS to produce SO4-⋅ and HO⋅. The radicals could destroy the structure of sludge cells and extracellular polymeric substance (EPS), transformed the hydrophilic and tightly bound EPS into soluble-EPS, degrade partial proteins and polysaccharides and released bound water. The negatively charged groups on sludge floc were dripped off by SO4-⋅/HO⋅ or neutralized with Fe2+, Fe3+, H+, or Fe(II)-SBC, leading to an increase in zeta potential to -2.24 mV and sludge destabilization. The residual Fe(II)-SBC served as a skeleton builder that decreased the compression coefficient of the sludge cake to 0.75. Under the combined functions, the CST and SRF were reduced by 70% and 82.7%, respectively, and Wc was reduced to 72.4%. The byproducts of Fe3+ and SO42- finally remained in sludge cake in the form of NaFeSi2O6 and CaSO4 |
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| Beschreibung: | Date Completed 30.01.2024 Date Revised 30.01.2024 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1479-487X |
| DOI: | 10.1080/09593330.2022.2129457 |