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231226s2022 xx |||||o 00| ||eng c |
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|a 10.1002/ejic.202100871
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|a eng
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|a Greb, Lutz
|e verfasserin
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|a Valence Tautomerism of p-Block Element Compounds - An Eligible Phenomenon for Main Group Catalysis?
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|c 2022
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 01.09.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH.
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|a Valence tautomerism has had a remarkable impact on several branches of transition metal chemistry. By switching between different valence tautomeric states, physicochemical properties and reactivities can be triggered reversibly. Is this phenomenon transferrable into the p-block - or is it already happening there? This Perspective collects observations of p-block element-ligand systems that might be assignable to valence tautomerism. Further, it discusses occurrences in p-block element compounds that exhibit the related effect of redox-induced electron transfer. As disclosed, the concept of valence tautomerism with p-block elements is at a very early stage. However, given the substantial disparity in the properties of those elements in different redox states, it might offer a valid extension for future developments in main group catalysis
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|a Journal Article
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|a Review
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|a Electromerism
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|a Main group elements
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|a Redox chemistry
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|a Valence tautomerism
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|a p-Block elements
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|i Enthalten in
|t European journal of inorganic chemistry
|d 1998
|g 2022(2022), 3 vom: 27. Jan., Seite e202100871
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|x 1434-1948
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|g volume:2022
|g year:2022
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|g day:27
|g month:01
|g pages:e202100871
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|u http://dx.doi.org/10.1002/ejic.202100871
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