Valence Tautomerism of p-Block Element Compounds - An Eligible Phenomenon for Main Group Catalysis?
© 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH.
| Veröffentlicht in: | European journal of inorganic chemistry. - 1998. - 2022(2022), 3 vom: 27. Jan., Seite e202100871 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | European journal of inorganic chemistry |
| Schlagworte: | Journal Article Review Electromerism Main group elements Redox chemistry Valence tautomerism p-Block elements |
| Zusammenfassung: | © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH. Valence tautomerism has had a remarkable impact on several branches of transition metal chemistry. By switching between different valence tautomeric states, physicochemical properties and reactivities can be triggered reversibly. Is this phenomenon transferrable into the p-block - or is it already happening there? This Perspective collects observations of p-block element-ligand systems that might be assignable to valence tautomerism. Further, it discusses occurrences in p-block element compounds that exhibit the related effect of redox-induced electron transfer. As disclosed, the concept of valence tautomerism with p-block elements is at a very early stage. However, given the substantial disparity in the properties of those elements in different redox states, it might offer a valid extension for future developments in main group catalysis |
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| Beschreibung: | Date Revised 01.09.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1434-1948 |
| DOI: | 10.1002/ejic.202100871 |