Identification of seven-coordinate LnIII ions in a LnIII[15-MCFe III N(shi)-5](OAc)2Cl species crystallized from methanol and pyridine
The title metallacrown (MC) complexes LnIII[15-MCFeIIIN(shi)-5](OAc)2CI(C5H5N)6 (Ln1), where OAc- is acetate, shi3- is salicylhydroximate, and Ln = Gd and Dy, were synthesized via a self-assembly reaction in methanol and pyridine. Single crystals were grown using slow evaporation and characterized u...
| Veröffentlicht in: | Journal of chemical crystallography. - 1998. - 52(2022), 2 vom: 15. Juni, Seite 152-160 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Journal of chemical crystallography |
| Schlagworte: | Journal Article Iron Lanthanides Metallacrown Self-assembly Seven-coordinate complexes |
| Zusammenfassung: | The title metallacrown (MC) complexes LnIII[15-MCFeIIIN(shi)-5](OAc)2CI(C5H5N)6 (Ln1), where OAc- is acetate, shi3- is salicylhydroximate, and Ln = Gd and Dy, were synthesized via a self-assembly reaction in methanol and pyridine. Single crystals were grown using slow evaporation and characterized using X-ray diffraction. Seven-coordinate capped octahedron geometries were observed for the lanthanide ion in both complexes, which is uncommon for trivalent lanthanide species. The 15-MC-5 is a ruffled metallacrown archetype similar to previously reported mixed-valent manganese metallacrowns |
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| Beschreibung: | Date Revised 28.08.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1074-1542 |
| DOI: | 10.1007/s10870-021-00900-6 |