Identification of seven-coordinate LnIII ions in a LnIII[15-MCFe III N(shi)-5](OAc)2Cl species crystallized from methanol and pyridine

The title metallacrown (MC) complexes LnIII[15-MCFeIIIN(shi)-5](OAc)2CI(C5H5N)6 (Ln1), where OAc- is acetate, shi3- is salicylhydroximate, and Ln = Gd and Dy, were synthesized via a self-assembly reaction in methanol and pyridine. Single crystals were grown using slow evaporation and characterized u...

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Bibliographische Detailangaben

Veröffentlicht in:	Journal of chemical crystallography. - 1998. - 52(2022), 2 vom: 15. Juni, Seite 152-160
1. Verfasser:	Biros, Elizabeth S (VerfasserIn)
Weitere Verfasser:	Ward, Cassandra L, Allen, Matthew J, Lutter, Jacob C
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2022
Zugriff auf das übergeordnete Werk:	Journal of chemical crystallography
Schlagworte:	Journal Article Iron Lanthanides Metallacrown Self-assembly Seven-coordinate complexes