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231226s2022 xx |||||o 00| ||eng c |
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|a 10.1021/acs.chemmater.1c03820
|2 doi
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|a pubmed24n1136.xml
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|a eng
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|a Bumstead, Alice M
|e verfasserin
|4 aut
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|a Post-Synthetic Modification of a Metal-Organic Framework Glass
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|c 2022
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 16.07.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2022 American Chemical Society.
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|a Melt-quenched metal-organic framework (MOF) glasses have gained significant interest as the first new category of glass reported in 50 years. In this work, an amine-functionalized zeolitic imidazolate framework (ZIF), denoted ZIF-UC-6, was prepared and demonstrated to undergo both melting and glass formation. The presence of an amine group resulted in a lower melting temperature compared to other ZIFs, while also allowing material properties to be tuned by post-synthetic modification (PSM). As a prototypical example, the ZIF glass surface was functionalized with octyl isocyanate, changing its behavior from hydrophilic to hydrophobic. PSM therefore provides a promising strategy for tuning the surface properties of MOF glasses
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|a Journal Article
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|a Pakamorė, Ignas
|e verfasserin
|4 aut
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|a Richards, Kieran D
|e verfasserin
|4 aut
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|a Thorne, Michael F
|e verfasserin
|4 aut
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|a Boyadjieva, Sophia S
|e verfasserin
|4 aut
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|a Castillo-Blas, Celia
|e verfasserin
|4 aut
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|a McHugh, Lauren N
|e verfasserin
|4 aut
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| 700 |
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|a Sapnik, Adam F
|e verfasserin
|4 aut
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| 700 |
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|a Keeble, Dean S
|e verfasserin
|4 aut
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| 700 |
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|a Keen, David A
|e verfasserin
|4 aut
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| 700 |
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|a Evans, Rachel C
|e verfasserin
|4 aut
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|a Forgan, Ross S
|e verfasserin
|4 aut
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| 700 |
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|a Bennett, Thomas D
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Chemistry of materials : a publication of the American Chemical Society
|d 1998
|g 34(2022), 5 vom: 08. März, Seite 2187-2196
|w (DE-627)NLM098194763
|x 0897-4756
|7 nnns
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|g volume:34
|g year:2022
|g number:5
|g day:08
|g month:03
|g pages:2187-2196
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|u http://dx.doi.org/10.1021/acs.chemmater.1c03820
|3 Volltext
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