Post-Synthetic Modification of a Metal-Organic Framework Glass

Post-Synthetic Modification of a Metal-Organic Framework Glass

© 2022 American Chemical Society.

Bibliographische Detailangaben
Veröffentlicht in:Chemistry of materials : a publication of the American Chemical Society. - 1998. - 34(2022), 5 vom: 08. März, Seite 2187-2196
1. Verfasser: Bumstead, Alice M (VerfasserIn)
Weitere Verfasser: Pakamorė, Ignas, Richards, Kieran D, Thorne, Michael F, Boyadjieva, Sophia S, Castillo-Blas, Celia, McHugh, Lauren N, Sapnik, Adam F, Keeble, Dean S, Keen, David A, Evans, Rachel C, Forgan, Ross S, Bennett, Thomas D
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Chemistry of materials : a publication of the American Chemical Society
Schlagworte:Journal Article
Beschreibung
Zusammenfassung:© 2022 American Chemical Society.
Melt-quenched metal-organic framework (MOF) glasses have gained significant interest as the first new category of glass reported in 50 years. In this work, an amine-functionalized zeolitic imidazolate framework (ZIF), denoted ZIF-UC-6, was prepared and demonstrated to undergo both melting and glass formation. The presence of an amine group resulted in a lower melting temperature compared to other ZIFs, while also allowing material properties to be tuned by post-synthetic modification (PSM). As a prototypical example, the ZIF glass surface was functionalized with octyl isocyanate, changing its behavior from hydrophilic to hydrophobic. PSM therefore provides a promising strategy for tuning the surface properties of MOF glasses
Beschreibung:Date Revised 16.07.2022
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:0897-4756
DOI:10.1021/acs.chemmater.1c03820