|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM336698054 |
| 003 |
DE-627 |
| 005 |
20231225232730.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2022 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202108333
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1122.xml
|
| 035 |
|
|
|a (DE-627)NLM336698054
|
| 035 |
|
|
|a (NLM)35137460
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Lin, Faxu
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Stepwise Energy Transfer
|b Near-Infrared Persistent Luminescence from Doped Polymeric Systems
|
| 264 |
|
1 |
|c 2022
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 15.04.2022
|
| 500 |
|
|
|a Date Revised 15.04.2022
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status MEDLINE
|
| 520 |
|
|
|a © 2022 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Organic near infrared (NIR) persistent-luminescence systems with bright and long-lived emission are highly valuable for applications in communication, imaging, and sensors. However, realizing these materials (especially lifetime over 0.1 s) is a challenge, mainly because of non-radiative quenching of their long-lived excitons. Herein, a universal strategy of stepwise Förster resonance energy transfer (FRET) for a bright NIR system with remarkable persistent luminescence (up to 0.2 s at 810 nm) is presented, based on a new triphenylene-dye-doped polymer (triphenylene-2-ylboronic acidpoly(vinyl alcohol) (TP@PVA)) with a persistent blue phosphorescence of 3.29 s. This persistent NIR luminescence is demonstrated for application not only in NIR anti-counterfeiting but also NIR bioimaging with penetrating a piece of skin as thick as 2.0 mm. By co-doping a red dye (such as Nile red) and an NIR dye Cyanine 7 (Cy7) into this doped PVA film, the shortage of spectral overlap between TP emission and Cy7 absorbance is successfully solved, through a stepwise FRET process involving triplet to singlet (TS)-FRET from TP to the intermediate red dye and then singlet to singlet (SS)-FRET to Cy7. It is noted that the efficiency of the upper TS-FRET is enhanced significantly by the lower SS-FRET, leading to high efficiencies for the continuous FRETs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Förster resonance energy transfer
|
| 650 |
|
4 |
|a near infrared
|
| 650 |
|
4 |
|a organic polymers
|
| 650 |
|
4 |
|a persistent luminescence
|
| 650 |
|
4 |
|a room-temperature phosphorescence
|
| 650 |
|
7 |
|a Coloring Agents
|2 NLM
|
| 650 |
|
7 |
|a Polymers
|2 NLM
|
| 700 |
1 |
|
|a Wang, Haiyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cao, Yifeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yu, Rujun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liang, Guodong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Huang, Huahua
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Mu, Yingxiao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Zhiyong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chi, Zhenguo
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 15 vom: 31. Apr., Seite e2108333
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:34
|g year:2022
|g number:15
|g day:31
|g month:04
|g pages:e2108333
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202108333
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 34
|j 2022
|e 15
|b 31
|c 04
|h e2108333
|