Discrimination of stereoisomers by one-dimensional 13 C NMR : All 16 stereoisomers of 4-hydroxy-α-tocopherol resolved

© 2021 DSM Food Specialties B.V. Magnetic Resonance in Chemistry published by John Wiley & Sons Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 59(2021), 11 vom: 11. Nov., Seite 1146-1153
1. Verfasser: Lankhorst, Peter P (VerfasserIn)
Weitere Verfasser: Duchateau, Alexander L L, Netscher, Thomas
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Letter
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520 |a All 16 resolved! A vitamin E-derived compound containing four chiral centers is the first example where all stereoisomers, that is, eight diastereomeric pairs of enantiomers, could be discriminated in a single NMR run. Measurement at 176 MHz in the presence of Pirkle's alcohol as a chiral solvating agent is a relatively robust, simple, easy-to-set-up, and fast method 
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