Discrimination of stereoisomers by one-dimensional 13 C NMR : All 16 stereoisomers of 4-hydroxy-α-tocopherol resolved
© 2021 DSM Food Specialties B.V. Magnetic Resonance in Chemistry published by John Wiley & Sons Ltd.
| Veröffentlicht in: | Magnetic resonance in chemistry : MRC. - 1985. - 59(2021), 11 vom: 11. Nov., Seite 1146-1153 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Magnetic resonance in chemistry : MRC |
| Schlagworte: | Letter |
| Zusammenfassung: | © 2021 DSM Food Specialties B.V. Magnetic Resonance in Chemistry published by John Wiley & Sons Ltd. All 16 resolved! A vitamin E-derived compound containing four chiral centers is the first example where all stereoisomers, that is, eight diastereomeric pairs of enantiomers, could be discriminated in a single NMR run. Measurement at 176 MHz in the presence of Pirkle's alcohol as a chiral solvating agent is a relatively robust, simple, easy-to-set-up, and fast method |
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| Beschreibung: | Date Completed 25.10.2021 Date Revised 25.10.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1097-458X |
| DOI: | 10.1002/mrc.5202 |