Universal Surface Coating with a Non-Phenolic Molecule, Sulfonated Pyrene

Nature-inspired small molecules such as catecholamines and polyphenols have gained a great deal of attention because of the exceptional surface-coating property that is applicable to many diverse substrates. Many researchers have conducted studies to expand molecular pools with surface-coating prope...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 37(2021), 23 vom: 15. Juni, Seite 7227-7236
1. Verfasser: Jeong, Yeonwoo (VerfasserIn)
Weitere Verfasser: Kang, Sung Min
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a Nature-inspired small molecules such as catecholamines and polyphenols have gained a great deal of attention because of the exceptional surface-coating property that is applicable to many diverse substrates. Many researchers have conducted studies to expand molecular pools with surface-coating properties, but previous reports have still been limited to phenolic molecules as surface-coating agents. In this study, we describe for the first time the material-independent coating properties of nonphenolic molecules, namely, sulfonated pyrenes with ZrIV ions. Owing to the binding capability with several oxygen-containing ligands, ZrIV can be used for the molecular assembly of sulfonated pyrenes. We also report on the mixing of multiple sulfonated pyrenes and ZrIV results in cross-linked complexes that can coat diverse solid substrates. The resulting coating can serve as a platform for grafting functional polysaccharides 
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