Universal Surface Coating with a Non-Phenolic Molecule, Sulfonated Pyrene
Nature-inspired small molecules such as catecholamines and polyphenols have gained a great deal of attention because of the exceptional surface-coating property that is applicable to many diverse substrates. Many researchers have conducted studies to expand molecular pools with surface-coating prope...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 37(2021), 23 vom: 15. Juni, Seite 7227-7236 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
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2021
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't |
| Zusammenfassung: | Nature-inspired small molecules such as catecholamines and polyphenols have gained a great deal of attention because of the exceptional surface-coating property that is applicable to many diverse substrates. Many researchers have conducted studies to expand molecular pools with surface-coating properties, but previous reports have still been limited to phenolic molecules as surface-coating agents. In this study, we describe for the first time the material-independent coating properties of nonphenolic molecules, namely, sulfonated pyrenes with ZrIV ions. Owing to the binding capability with several oxygen-containing ligands, ZrIV can be used for the molecular assembly of sulfonated pyrenes. We also report on the mixing of multiple sulfonated pyrenes and ZrIV results in cross-linked complexes that can coat diverse solid substrates. The resulting coating can serve as a platform for grafting functional polysaccharides |
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| Beschreibung: | Date Completed 24.06.2021 Date Revised 24.06.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.1c00784 |