Study of hydrolytic kinetics of the hexachlorostannate anion by two-dimensional 119 Sn exchange spectroscopy

Copyright © 1989 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 27(1989), 9 vom: 25. Sept., Seite 836-840
1. Verfasser: Mao, Xi-An (VerfasserIn)
Weitere Verfasser: You, Xiao-Zeng, Dai, An-Bang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 1989
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article 2D 119Sn EXSY Equilibrium constants Hexachlorostannate anion Hydrolysis Rate constants
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520 |a Two-dimensional 119 Sn exchange spectroscopy was applied to study the hydrolytic kinetics of the hexachloro-stannate anion, SnCl6 2- . Two 119 Sn exchange spectra for SnCl4 · 5H2 O solutions with various HCl concentrations are presented. Magnetization exchanges, which are related to the hydrolysis processes, occur in the SnCl6 2- hydrolysis series. The exchange rate constants, the hydrolysis rate constants and the hydrolysis equilibrium constants were evaluated 
650 4 |a Journal Article 
650 4 |a 2D 119Sn EXSY 
650 4 |a Equilibrium constants 
650 4 |a Hexachlorostannate anion 
650 4 |a Hydrolysis 
650 4 |a Rate constants 
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700 1 |a Dai, An-Bang  |e verfasserin  |4 aut 
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