Study of hydrolytic kinetics of the hexachlorostannate anion by two-dimensional 119 Sn exchange spectroscopy
Copyright © 1989 John Wiley & Sons, Ltd.
| Veröffentlicht in: | Magnetic resonance in chemistry : MRC. - 1985. - 27(1989), 9 vom: 25. Sept., Seite 836-840 |
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| Weitere Verfasser: | , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
1989
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| Zugriff auf das übergeordnete Werk: | Magnetic resonance in chemistry : MRC |
| Schlagworte: | Journal Article 2D 119Sn EXSY Equilibrium constants Hexachlorostannate anion Hydrolysis Rate constants |
| Zusammenfassung: | Copyright © 1989 John Wiley & Sons, Ltd. Two-dimensional 119 Sn exchange spectroscopy was applied to study the hydrolytic kinetics of the hexachloro-stannate anion, SnCl6 2- . Two 119 Sn exchange spectra for SnCl4 · 5H2 O solutions with various HCl concentrations are presented. Magnetization exchanges, which are related to the hydrolysis processes, occur in the SnCl6 2- hydrolysis series. The exchange rate constants, the hydrolysis rate constants and the hydrolysis equilibrium constants were evaluated |
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| Beschreibung: | Date Revised 26.05.2021 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1097-458X |
| DOI: | 10.1002/mrc.1260270905 |