Microgel-Stabilized Hydroxypropyl Methylcellulose and Dextran Water-in-Water Emulsion : Influence of pH, Ionic Strength, and Temperature

A stable water-in-water (W/W) emulsion was formed by mixing dextran and hydroxypropyl methylcellulose (HPMC) with addition of β-lactoglobulin (Blg) microgels. The microstructure and stability of the W/W emulsion were investigated under different conditions. The microgels accumulating at the liquid-l...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 37(2021), 18 vom: 11. Mai, Seite 5617-5626
1. Verfasser: Zhang, Jinglin (VerfasserIn)
Weitere Verfasser: Mei, Lei, Ma, Peihua, Li, Yuan, Yuan, Yang, Zeng, Qing-Zhu, Wang, Qin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S.
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520 |a A stable water-in-water (W/W) emulsion was formed by mixing dextran and hydroxypropyl methylcellulose (HPMC) with addition of β-lactoglobulin (Blg) microgels. The microstructure and stability of the W/W emulsion were investigated under different conditions. The microgels accumulating at the liquid-liquid interface led to a stable emulsion at pH 3-5, where the microgels carried positive charges. When the pH was increased above the pI of microgels (∼pH 5), the emulsion was destabilized because the microgels tended to stay in the continuous phase (i.e., dextran) rather than at the interface. The HPMC-in-dextran emulsions were stable under ionic strength levels up to 300 mM. The HPMC-in-dextran emulsion stabilized by Blg microgels was thermally stable, and the heat treatment promoted partial Blg microgel particle-particle fusion on the surface of HPMC droplets at 90 °C. Electrostatic and hydrophobic interactions between dextran and HPMC phase were further investigated to understand the microgels' accumulation at the liquid-liquid interface 
650 4 |a Journal Article 
650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
700 1 |a Mei, Lei  |e verfasserin  |4 aut 
700 1 |a Ma, Peihua  |e verfasserin  |4 aut 
700 1 |a Li, Yuan  |e verfasserin  |4 aut 
700 1 |a Yuan, Yang  |e verfasserin  |4 aut 
700 1 |a Zeng, Qing-Zhu  |e verfasserin  |4 aut 
700 1 |a Wang, Qin  |e verfasserin  |4 aut 
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