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|a 10.1021/acs.organomet.1c00030
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|a eng
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|a Pabst, Tyler P
|e verfasserin
|4 aut
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|a A Tutorial on Selectivity Determination in C(sp2)-H Oxidative Addition of Arenes by Transition Metal Complexes
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|c 2021
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|a Text
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|a ƒaComputermedien
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|a Date Revised 21.04.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 American Chemical Society.
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|a A Tutorial on factors that determine the selectivity in C(sp2)-H activation and functionalization reactions involving two-electron oxidative addition processes with transition metals is presented. The interplay of the thermodynamics of C(sp2)-H oxidative addition and kinetic influences upon regioselectivity are presented alongside pedagogically valuable experimental and computational results from the literature. Mechanisms and energetics of chelate-assisted C(sp2)-H oxidative addition are examined, as are concepts related to chemoselectivity in the oxidative addition of C(sp2)-H or C(sp2)-X (X = F, Cl, Br, I) bonds with aryl halide substrates
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|a Journal Article
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|a Chirik, Paul J
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|t Organometallics
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|g 40(2021), 7 vom: 12. Apr., Seite 813-831
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