A Tutorial on Selectivity Determination in C(sp2)-H Oxidative Addition of Arenes by Transition Metal Complexes
© 2021 American Chemical Society.
| Veröffentlicht in: | Organometallics. - 1998. - 40(2021), 7 vom: 12. Apr., Seite 813-831 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Organometallics |
| Schlagworte: | Journal Article Review |
| Zusammenfassung: | © 2021 American Chemical Society. A Tutorial on factors that determine the selectivity in C(sp2)-H activation and functionalization reactions involving two-electron oxidative addition processes with transition metals is presented. The interplay of the thermodynamics of C(sp2)-H oxidative addition and kinetic influences upon regioselectivity are presented alongside pedagogically valuable experimental and computational results from the literature. Mechanisms and energetics of chelate-assisted C(sp2)-H oxidative addition are examined, as are concepts related to chemoselectivity in the oxidative addition of C(sp2)-H or C(sp2)-X (X = F, Cl, Br, I) bonds with aryl halide substrates |
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| Beschreibung: | Date Revised 21.04.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 0276-7333 |
| DOI: | 10.1021/acs.organomet.1c00030 |