Stable Unbiased Photo-Electrochemical Overall Water Splitting Exceeding 3% Efficiency via Covalent Triazine Framework/Metal Oxide Hybrid Photoelectrodes
© 2021 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 15 vom: 10. Apr., Seite e2008264 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Review covalent triazine frameworks heterojunctions photo-electrochemical cells surface protection water splitting |
| Zusammenfassung: | © 2021 Wiley-VCH GmbH. Photo-electrochemical (PEC) water splitting systems using oxide-based photoelectrodes are highly attractive for solar-to-chemical energy conversion. However, despite decades-long efforts, it is still challenging to develop efficient and stable photoelectrodes for practical applications. Here, thin layers of covalent triazine frameworks (CTF-BTh) containing a bithiophene moiety are conformably deposited onto the surfaces of a Cu2 O photocathode and a Mo-doped BiVO4 photoanode via electropolymerization to construct new hybrid photoelectrodes, successfully addressing the efficiency and stability issues. The CTF-BTh possesses a suitable band structure to form favorable band edge alignment with each metal oxide, creating a p-n junction and a staggered type-II heterojunction with Cu2 O and Mo-doped BiVO4 , respectively. Thus, the as-fabricated hybrid photoelectrodes exhibit substantially increased PEC performances. Meanwhile, the CTF-BTh film also serves as an effective corrosion-resistant overlayer for both photoelectrodes to inhibit photocorrosion and enable long-term operation for 150 h with only ≈10% loss in photocurrent densities. Furthermore, a stand-alone unbiased PEC tandem device comprising CTF-BTh-coated photoelectrodes exhibits 3.70% solar-to-hydrogen conversion efficiency. Even after continuous operation for 120 h, the efficiency can still retain at 3.24% |
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| Beschreibung: | Date Revised 14.04.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202008264 |