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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.0c02807
|2 doi
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|a pubmed24n1059.xml
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
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|a Sakamoto, Hiromu
|e verfasserin
|4 aut
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| 245 |
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|a Surface Freezing of Cetyltrimethylammonium Chloride-Hexadecanol Mixed Adsorbed Film at Dodecane-Water Interface
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 08.12.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The surface freezing transition of a mixed adsorbed film containing cetyltrimethylammonium chloride (CTAC) and n-hexadecanol (C16OH) was utilized at the dodecane-water interface to control the stability of oil-in-water (O/W) emulsions. The corresponding surface frozen and surface liquid mixed adsorbed films were characterized using interfacial tensiometry and X-ray reflectometry. The emulsion samples prepared in the temperature range of the surface frozen and surface liquid phases showed a clear difference in their stability: the emulsion volume decreased continuously right after the emulsification in the surface liquid region, while it remained constant or decreased at a much slower rate in the surface frozen region. Compared to the previously examined CTAC-tetradecane mixed adsorbed film, the surface freezing temperature increased from 9.5 to 25.0 °C due to the better chain matching between CTAC and C16OH and higher surface activity of C16OH. This then renders such systems much more attractive for practical applications
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|a Journal Article
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|a Masunaga, Akihiro
|e verfasserin
|4 aut
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|a Takiue, Takanori
|e verfasserin
|4 aut
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| 700 |
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|a Tanida, Hajime
|e verfasserin
|4 aut
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| 700 |
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|a Uruga, Tomoya
|e verfasserin
|4 aut
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|a Nitta, Kiyofumi
|e verfasserin
|4 aut
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|a Prause, Albert
|e verfasserin
|4 aut
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|a Gradzielski, Michael
|e verfasserin
|4 aut
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|a Matsubara, Hiroki
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 36(2020), 48 vom: 08. Dez., Seite 14811-14818
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:36
|g year:2020
|g number:48
|g day:08
|g month:12
|g pages:14811-14818
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|u http://dx.doi.org/10.1021/acs.langmuir.0c02807
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