Liquid-Metal-Templated Synthesis of 2D Graphitic Materials at Room Temperature

Bibliographische Detailangaben
Veröffentlicht in:	Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 29 vom: 03. Juli, Seite e2001997
1. Verfasser:	Mayyas, Mohannad (VerfasserIn)
Weitere Verfasser:	Li, Hongzhe, Kumar, Priyank, Ghasemian, Mohammad B, Yang, Jiong, Wang, Yifang, Lawes, Douglas J, Han, Jialuo, Saborio, Maricruz G, Tang, Jianbo, Jalili, Rouhollah, Lee, Sun Hwa, Seong, Won Kyung, Russo, Salvy P, Esrafilzadeh, Dorna, Daeneke, Torben, Kaner, Richard B, Ruoff, Rodney S, Kalantar-Zadeh, Kourosh
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2020
Zugriff auf das übergeordnete Werk:	Advanced materials (Deerfield Beach, Fla.)
Schlagworte:	Journal Article 2D materials carbon templating electrocatalysis liquid metals liquid-liquid interfaces

Beschreibung
Zusammenfassung:	© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Room-temperature synthesis of 2D graphitic materials (2D-GMs) remains an elusive aim, especially with electrochemical means. Here, it is shown that liquid metals render this possible as they offer catalytic activity and an ultrasmooth templating interface that promotes Frank-van der Merwe regime growth, while allowing facile exfoliation due to the absence of interfacial forces as a nonpolar liquid. The 2D-GMs are formed at low onset potential and can be in situ doped depending on the choice of organic precursors and the electrochemical set-up. The materials are tuned to exhibit porous or pinhole-free morphologies and are engineered for their degree of oxidation and number of layers. The proposed liquid-metal-based room-temperature electrochemical route can be expanded to many other 2D materials
Beschreibung:	Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE
ISSN:	1521-4095
DOI:	10.1002/adma.202001997