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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202000030
|2 doi
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|a pubmed24n1031.xml
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|a (DE-627)NLM309473721
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|a (NLM)32363768
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Deng, Tao
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Tuning the Anode-Electrolyte Interface Chemistry for Garnet-Based Solid-State Li Metal Batteries
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Lithium (Li) metal is a promising candidate as the anode for high-energy-density solid-state batteries. However, interface issues, including large interfacial resistance and the generation of Li dendrites, have always frustrated the attempt to commercialize solid-state Li metal batteries (SSLBs). Here, it is reported that infusing garnet-type solid electrolytes (GSEs) with the air-stable electrolyte Li3 PO4 (LPO) dramatically reduces the interfacial resistance to ≈1 Ω cm2 and achieves a high critical current density of 2.2 mA cm-2 under ambient conditions due to the enhanced interfacial stability to the Li metal anode. The coated and infused LPO electrolytes not only improve the mechanical strength and Li-ion conductivity of the grain boundaries, but also form a stable Li-ion conductive but electron-insulating LPO-derived solid-electrolyte interphase between the Li metal and the GSE. Consequently, the growth of Li dendrites is eliminated and the direct reduction of the GSE by Li metal over a long cycle life is prevented. This interface engineering approach together with grain-boundary modification on GSEs represents a promising strategy to revolutionize the anode-electrolyte interface chemistry for SSLBs and provides a new design strategy for other types of solid-state batteries
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|a Journal Article
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|a garnet electrolytes
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4 |
|a interfacial chemistry
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| 650 |
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4 |
|a lithium dendrites
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| 650 |
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4 |
|a solid-electrolyte interphase
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| 650 |
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4 |
|a solid-state batteries
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| 700 |
1 |
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|a Ji, Xiao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhao, Yang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Cao, Longsheng
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Shuang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Hwang, Sooyeon
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Luo, Chao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Pengfei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Jia, Haiping
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Fan, Xiulin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lu, Xiaochuan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Su, Dong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Sun, Xueliang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, Chunsheng
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Ji-Guang
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 32(2020), 23 vom: 03. Juni, Seite e2000030
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
1 |
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|g volume:32
|g year:2020
|g number:23
|g day:03
|g month:06
|g pages:e2000030
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| 856 |
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|u http://dx.doi.org/10.1002/adma.202000030
|3 Volltext
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