Characterization of the Hydration Process of Phospholipid-Mimetic Polymers Using Air-Injection-Mediated Liquid Exclusion Methods

2-Methacryloyloxyethyl phosphorylcholine (MPC) polymers including hydrophobic units such as poly(MPC-co-butyl methacrylate) (PMB) and poly(MPC-co-dodecyl methacrylate) (PMD) are used as coating agents for medical devices because of their antifouling effects. In this study, the whole hydration proces...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 36(2020), 20 vom: 26. Mai, Seite 5626-5632
1. Verfasser: Katayama, Risa (VerfasserIn)
Weitere Verfasser: Tanaka, Nobuyuki, Takagi, Yusuke, Shiraishi, Kohei, Tanaka, Yo, Matsumoto, Akikazu, Kojima, Chie
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a 2-Methacryloyloxyethyl phosphorylcholine (MPC) polymers including hydrophobic units such as poly(MPC-co-butyl methacrylate) (PMB) and poly(MPC-co-dodecyl methacrylate) (PMD) are used as coating agents for medical devices because of their antifouling effects. In this study, the whole hydration process of MPC polymer-coated surfaces was investigated using air-injection-mediated liquid exclusion (AILE) methods in which the liquid exclusion diameter during air injection was correlated to the water-repelling property. The prejetted and standard AILE methods showed the initial change from a dry to a wet state and the swelling behaviors of the MPC polymers, respectively. The liquid exclusion diameter of the MPC polymer-coated surfaces increased with an increase in the immersion time in various aqueous solutions such as deionized water, phosphate-buffered saline (PBS), and cell culture media. Moreover, the liquid exclusion diameter of the PMD-coated surface was larger than that of the PMB-coated one. Ellipsometry directly indicated the polymer layers swollen in water. Scanning probe microscopy (SPM) revealed that nanosized protuberances were formed in water, especially at the PMD-coated surface. The different swelling behaviors of these MPC polymer-coated surfaces affected the liquid exclusion diameters. Thus, the AILE methods are a powerful tool to elucidate the hydration process in various liquid media 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
700 1 |a Tanaka, Nobuyuki  |e verfasserin  |4 aut 
700 1 |a Takagi, Yusuke  |e verfasserin  |4 aut 
700 1 |a Shiraishi, Kohei  |e verfasserin  |4 aut 
700 1 |a Tanaka, Yo  |e verfasserin  |4 aut 
700 1 |a Matsumoto, Akikazu  |e verfasserin  |4 aut 
700 1 |a Kojima, Chie  |e verfasserin  |4 aut 
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