Synthesis of Palladium-Based CrystallineAmorphous Core-Shell Nanoplates for Highly Efficient Ethanol Oxidation

Bibliographische Detailangaben
Veröffentlicht in:	Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 21 vom: 26. Mai, Seite e2000482
1. Verfasser:	Yin, Peng-Fei (VerfasserIn)
Weitere Verfasser:	Zhou, Ming, Chen, Junze, Tan, Chaoliang, Liu, Guigao, Ma, Qinglang, Yun, Qinbai, Zhang, Xiao, Cheng, Hongfei, Lu, Qipeng, Chen, Bo, Chen, Ye, Zhang, Zhicheng, Huang, Jingtao, Hu, Dianyi, Wang, Jie, Liu, Qing, Luo, Zhiyong, Liu, Zhengqing, Ge, Yiyao, Wu, Xue-Jun, Du, Xi-Wen, Zhang, Hua
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2020
Zugriff auf das übergeordnete Werk:	Advanced materials (Deerfield Beach, Fla.)
Schlagworte:	Journal Article amorphous ethanol oxidation reaction heterostructures nanoplates

Beschreibung
Zusammenfassung:	© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Phase engineering of nanomaterials (PEN) offers a promising route to rationally tune the physicochemical properties of nanomaterials and further enhance their performance in various applications. However, it remains a great challenge to construct well-defined crystallineamorphous core-shell heterostructured nanomaterials with the same chemical components. Herein, the synthesis of binary (Pd-P) crystalline@amorphous heterostructured nanoplates using Cu3- χ P nanoplates as templates, via cation exchange, is reported. The obtained nanoplate possesses a crystalline core and an amorphous shell with the same elemental components, referred to as c-Pd-P@a-Pd-P. Moreover, the obtained c-Pd-P@a-Pd-P nanoplates can serve as templates to be further alloyed with Ni, forming ternary (Pd-Ni-P) crystalline@amorphous heterostructured nanoplates, referred to as c-Pd-Ni-P@a-Pd-Ni-P. The atomic content of Ni in the c-Pd-Ni-P@a-Pd-Ni-P nanoplates can be tuned in the range from 9.47 to 38.61 at%. When used as a catalyst, the c-Pd-Ni-P@a-Pd-Ni-P nanoplates with 9.47 at% Ni exhibit excellent electrocatalytic activity toward ethanol oxidation, showing a high mass current density up to 3.05 A mgPd -1 , which is 4.5 times that of the commercial Pd/C catalyst (0.68 A mgPd -1 )
Beschreibung:	Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE
ISSN:	1521-4095
DOI:	10.1002/adma.202000482