Aerosol Synthesis of High Entropy Alloy Nanoparticles

Homogeneously mixing multiple metal elements within a single particle may offer new material property functionalities. High entropy alloys (HEAs), nominally defined as structures containing five or more well-mixed metal elements, are being explored at the nanoscale, but the scale-up to enable their...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 36(2020), 8 vom: 03. März, Seite 1985-1992
1. Verfasser: Yang, Yong (VerfasserIn)
Weitere Verfasser: Song, Boao, Ke, Xiang, Xu, Feiyu, Bozhilov, Krassimir N, Hu, Liangbing, Shahbazian-Yassar, Reza, Zachariah, Michael R
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Homogeneously mixing multiple metal elements within a single particle may offer new material property functionalities. High entropy alloys (HEAs), nominally defined as structures containing five or more well-mixed metal elements, are being explored at the nanoscale, but the scale-up to enable their industrial application is an extremely challenging problem. Here, we report an aerosol droplet-mediated technique toward scalable synthesis of HEA nanoparticles with atomic-level mixing of immiscible metal elements. An aqueous solution of metal salts is nebulized to generate ∼1 μm aerosol droplets, which when subjected to fast heating/quenching result in decomposition of the precursors and freezing-in of the zero-valent metal atoms. Atomic-level resolution scanning transmission electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis reveals that all metal elements in the nanoparticles are homogeneously mixed at the atomic level. We believe that this approach offers a facile and flexible aerosol droplet-mediated synthesis technique that will ultimately enable bulk processing starting from a particulate HEA 
650 4 |a Journal Article 
700 1 |a Song, Boao  |e verfasserin  |4 aut 
700 1 |a Ke, Xiang  |e verfasserin  |4 aut 
700 1 |a Xu, Feiyu  |e verfasserin  |4 aut 
700 1 |a Bozhilov, Krassimir N  |e verfasserin  |4 aut 
700 1 |a Hu, Liangbing  |e verfasserin  |4 aut 
700 1 |a Shahbazian-Yassar, Reza  |e verfasserin  |4 aut 
700 1 |a Zachariah, Michael R  |e verfasserin  |4 aut 
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