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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1177/0734242X19879224
|2 doi
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|a pubmed24n1006.xml
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Yao, Zhitong
|e verfasserin
|4 aut
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| 245 |
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|a Kinetic modeling study on the combustion treatment of cathode from spent lithium-ion batteries
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 30.12.2019
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|a Date Revised 30.12.2019
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Thermal treatment offers an alternative method for the separation of aluminum foil and cathode materials during spent lithium-ion batteries recycling. In this work, the combustion kinetic of cathode was studied based on six model-free (isoconversional) methods, namely Flynn-Wall-Ozawa (FWO), Friedman, Kissinger-Akahira-Sunose, Starink, Tang, and Boswell methods. The possible decomposition mechanism was also probed using a master-plots method (Criado method). Thermogravimetric analysis showed that the whole thermal process could be divided into three stages with temperatures of 37-578°C, 578-849°C, and 849-1000°C. The activation energy (Eα) derived from these model-free methods displayed the same trend, gradually increasing with a conversion range of 0.002-0.013, and significantly elevating beyond this range. The coefficients from the FWO method were larger, and the resulted Eα fell into the range of 10.992-40.298 kJ/mol with an average value of 20.228 kJ/mol. Comparing the theoretical master plots with an experimental curve, the thermal decomposition of cathode could be better described by the geometric contraction models
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|a Journal Article
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|a Criado method
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|a Spent lithium-ion batteries
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|a cathode material
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|a model-free method
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|a polyvinylidene fluoride
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|a Lithium
|2 NLM
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|a 9FN79X2M3F
|2 NLM
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| 700 |
1 |
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|a Yu, Shaoqi
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Su, Weiping
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wu, Daidai
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wu, Weihong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Tang, Junhong
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
|d 1991
|g 38(2020), 1 vom: 01. Jan., Seite 100-106
|w (DE-627)NLM098164791
|x 1096-3669
|7 nnns
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| 773 |
1 |
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|g volume:38
|g year:2020
|g number:1
|g day:01
|g month:01
|g pages:100-106
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|u http://dx.doi.org/10.1177/0734242X19879224
|3 Volltext
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