Upconversion NanoparticlesCarbon Dots@Meso-SiO2 Sandwiched Core-Shell Nanohybrids with Tunable Dual-Mode Luminescence for 3D Anti-Counterfeiting Barcodes

Development of advanced fluorescent materials for constructing a secure and unclonable encryption is urgently required; however, their application in anti-counterfeiting applications is a great challenge. In this work, we proposed and synthesized a new type of upconversion nanoparticlescarbon dots@m...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 35(2019), 35 vom: 03. Sept., Seite 11503-11511
1. Verfasser: Tan, Haihu (VerfasserIn)
Weitere Verfasser: Gong, Guo, Xie, Shaowen, Song, Ya, Zhang, Changfan, Li, Na, Zhang, Dong, Xu, Lijian, Xu, Jianxiong, Zheng, Jie
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Development of advanced fluorescent materials for constructing a secure and unclonable encryption is urgently required; however, their application in anti-counterfeiting applications is a great challenge. In this work, we proposed and synthesized a new type of upconversion nanoparticlescarbon dots@meso-SiO2 nanohybrids by integrating two fluorescent materials of lanthanide-doped NaYF4 upconversion nanoparticles (UCNPs) and carbon dots (CDs) into mesoporous silica (mSiO2) to produce a novel sandwichlike core-shell structure and a dual-mode fluorescence from UCNPs and CDs. By tailoring the UCNP core of different upconversion luminescence, all three kinds of dual-mode luminescent UCNPs@CDs@mSiO2 nanohybrids exhibited typical RGB upconversion luminescence under a 980 nm laser and blue downconversion luminescence under a 365 nm UV light. Due to strong the hydrophilic nature of the nanohybrids, they can be further fabricated into environmentally benign luminescent inks for creating highly secured, fluorescent-based, three-dimensional anti-counterfeiting barcodes via inkjet printing. The resultant UCNPs@CDs@mSiO2 inks with a dual-mode and tunable luminescence nature endow the inkjet-printing barcodes with an extremely high encoding capacity and high security. Such dual-mode fluorescent inks and barcodes are simple to fabricate, easy to view, efficient for coding, and difficult to clone, thus making them promising nanomaterials for anti-counterfeiting applications 
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700 1 |a Gong, Guo  |e verfasserin  |4 aut 
700 1 |a Xie, Shaowen  |e verfasserin  |4 aut 
700 1 |a Song, Ya  |e verfasserin  |4 aut 
700 1 |a Zhang, Changfan  |e verfasserin  |4 aut 
700 1 |a Li, Na  |e verfasserin  |4 aut 
700 1 |a Zhang, Dong  |e verfasserin  |4 aut 
700 1 |a Xu, Lijian  |e verfasserin  |4 aut 
700 1 |a Xu, Jianxiong  |e verfasserin  |4 aut 
700 1 |a Zheng, Jie  |e verfasserin  |4 aut 
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