Upconversion NanoparticlesCarbon Dots@Meso-SiO2 Sandwiched Core-Shell Nanohybrids with Tunable Dual-Mode Luminescence for 3D Anti-Counterfeiting Barcodes
Development of advanced fluorescent materials for constructing a secure and unclonable encryption is urgently required; however, their application in anti-counterfeiting applications is a great challenge. In this work, we proposed and synthesized a new type of upconversion nanoparticlescarbon dots@m...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 35(2019), 35 vom: 03. Sept., Seite 11503-11511 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2019
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Development of advanced fluorescent materials for constructing a secure and unclonable encryption is urgently required; however, their application in anti-counterfeiting applications is a great challenge. In this work, we proposed and synthesized a new type of upconversion nanoparticlescarbon dots@meso-SiO2 nanohybrids by integrating two fluorescent materials of lanthanide-doped NaYF4 upconversion nanoparticles (UCNPs) and carbon dots (CDs) into mesoporous silica (mSiO2) to produce a novel sandwichlike core-shell structure and a dual-mode fluorescence from UCNPs and CDs. By tailoring the UCNP core of different upconversion luminescence, all three kinds of dual-mode luminescent UCNPs@CDs@mSiO2 nanohybrids exhibited typical RGB upconversion luminescence under a 980 nm laser and blue downconversion luminescence under a 365 nm UV light. Due to strong the hydrophilic nature of the nanohybrids, they can be further fabricated into environmentally benign luminescent inks for creating highly secured, fluorescent-based, three-dimensional anti-counterfeiting barcodes via inkjet printing. The resultant UCNPs@CDs@mSiO2 inks with a dual-mode and tunable luminescence nature endow the inkjet-printing barcodes with an extremely high encoding capacity and high security. Such dual-mode fluorescent inks and barcodes are simple to fabricate, easy to view, efficient for coding, and difficult to clone, thus making them promising nanomaterials for anti-counterfeiting applications |
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| Beschreibung: | Date Revised 23.09.2019 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.9b01919 |