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231225s2019 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.9b00493
|2 doi
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|a eng
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|a Demaude, A
|e verfasserin
|4 aut
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|a Atmospheric Pressure Plasma Deposition of Hydrophilic/Phobic Patterns and Thin Film Laminates on Any Surface
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|c 2019
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|a Text
|b txt
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 23.09.2019
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Patterned and layered hydrophilic/phobic coatings were deposited on multiple surfaces using nonfluorinated precursors (AA, acrylic acid; PMA, propargyl methacrylate) with an atmospheric pressure dielectric barrier discharge operating in open air. Water contact angles of the resulting films could be tuned from <5° (superhydrophilic) to >135° (very hydrophobic) by adjusting the AA/PMA feed ratio and/or via postdeposition exposure of films to an Ar/O2 plasma treatment. Coatings could be applied to any surface and were seen to be water stable, due in large part to cross-linking induced from the reactivity of the PMA pendant groups. Hybrid hydrophilic/phobic patterns at submillimeter length scales, and philic/phobic/philic laminates were produced using a shadow mask and sequential deposition, respectively. Chemical heterogeneity of films was assessed using XPS, SIMS, and micro-IR imaging and suggest that localization of COOH and OH groups are primarily responsible for hydrophilicity. Overall, this work demonstrates that atmospheric pressure plasma polymerization is a simple and scalable method for robust and tunable control of wettability of surfaces of all kinds
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|a Journal Article
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|a Poleunis, C
|e verfasserin
|4 aut
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|a Goormaghtigh, E
|e verfasserin
|4 aut
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|a Viville, P
|e verfasserin
|4 aut
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|a Lazzaroni, R
|e verfasserin
|4 aut
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|a Delcorte, A
|e verfasserin
|4 aut
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|a Gordon, M
|e verfasserin
|4 aut
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|a Reniers, F
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 35(2019), 30 vom: 30. Juli, Seite 9677-9683
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:35
|g year:2019
|g number:30
|g day:30
|g month:07
|g pages:9677-9683
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|u http://dx.doi.org/10.1021/acs.langmuir.9b00493
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