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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/ejic.201701413
|2 doi
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|a pubmed24n1472.xml
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|a (DE-627)NLM296768324
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|a (NLM)31057330
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|a DE-627
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|c DE-627
|e rakwb
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|a eng
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|a de Aguiar, Sara R M M
|e verfasserin
|4 aut
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|a Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes
|b Interplay between Water and Molecular Oxygen
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 16.07.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The synthesis of cationic mono oxo MoIV PNP pincer complexes of the type [Mo(PNPMe-iPr)(O)X]+ (X = I, Br) from [Mo(PNPMe-iPr)(CO)X2] is described. These compounds are coordinatively unsaturated and feature a strong Mo≡O triple bond. The formation of these complexes proceeds via cationic 14e intermediates [Mo(PNPMe-iPr)(CO)X]+ and requires both molecular oxygen and water. ESI MS measurements with 18O labeled water (H2 18O) and molecular oxygen (18O2) indicates that water plays a crucial role in the formation of the Mo≡O bond. A plausible mechanism based on DFT calculations is provided. The X-ray structure of [Mo(PNPMe-iPr)(O)I]SbF6 is presented
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|a Journal Article
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|a Ligand effects
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|a Molybdenum
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|a Oxo complexes
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|a Phosphines
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|a Pincer ligands
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|a Öztopcu, Özgür
|e verfasserin
|4 aut
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|a Troiani, Anna
|e verfasserin
|4 aut
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|a de Petris, Giulia
|e verfasserin
|4 aut
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|a Weil, Matthias
|e verfasserin
|4 aut
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|a Stöger, Berthold
|e verfasserin
|4 aut
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|a Pittenauer, Ernst
|e verfasserin
|4 aut
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|a Allmaier, Günter
|e verfasserin
|4 aut
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|a Veiros, Luis F
|e verfasserin
|4 aut
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|a Kirchner, Karl
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t European journal of inorganic chemistry
|d 1998
|g 2018(2018), 7 vom: 21. Feb., Seite 876-884
|w (DE-627)NLM098272756
|x 1434-1948
|7 nnns
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| 773 |
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|g volume:2018
|g year:2018
|g number:7
|g day:21
|g month:02
|g pages:876-884
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|u http://dx.doi.org/10.1002/ejic.201701413
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