Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes : Interplay between Water and Molecular Oxygen
The synthesis of cationic mono oxo MoIV PNP pincer complexes of the type [Mo(PNPMe-iPr)(O)X]+ (X = I, Br) from [Mo(PNPMe-iPr)(CO)X2] is described. These compounds are coordinatively unsaturated and feature a strong Mo≡O triple bond. The formation of these complexes proceeds via cationic 14e intermed...
Ausführliche Beschreibung
Bibliographische Detailangaben
| Veröffentlicht in: | European journal of inorganic chemistry. - 1998. - 2018(2018), 7 vom: 21. Feb., Seite 876-884
|
|---|
| 1. Verfasser: |
de Aguiar, Sara R M M
(VerfasserIn) |
|---|
| Weitere Verfasser: |
Öztopcu, Özgür,
Troiani, Anna,
de Petris, Giulia,
Weil, Matthias,
Stöger, Berthold,
Pittenauer, Ernst,
Allmaier, Günter,
Veiros, Luis F,
Kirchner, Karl |
|---|
| Format: | Online-Aufsatz
|
|---|
| Sprache: | English |
|---|
| Veröffentlicht: |
2018
|
|---|
| Zugriff auf das übergeordnete Werk: | European journal of inorganic chemistry
|
|---|
| Schlagworte: | Journal Article
Ligand effects
Molybdenum
Oxo complexes
Phosphines
Pincer ligands |
|---|