Femtosecond Laser-Induced Underwater Superoleophobic Surfaces with Reversible pH-Responsive Wettability

Wettability-switchable surfaces have become a research hotspot because they can exhibit different superwetting states. In this paper, the copper surfaces with pH-responsive underwater-oil wettability were prepared by femtosecond laser treatment and subsequent chemical modification. The resultant sur...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 9 vom: 05. März, Seite 3295-3301
1. Verfasser: Zhang, Jingzhou (VerfasserIn)
Weitere Verfasser: Yong, Jiale, Yang, Qing, Chen, Feng, Hou, Xun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Wettability-switchable surfaces have become a research hotspot because they can exhibit different superwetting states. In this paper, the copper surfaces with pH-responsive underwater-oil wettability were prepared by femtosecond laser treatment and subsequent chemical modification. The resultant surfaces showed underwater superoleophobicity in alkaline solutions but quasi-superoleophilicity in acidic solutions. The contact angles of an underwater-oil droplet on the resultant surfaces could be reversibly tuned between 157° and 12° by changing the pH of aqueous solutions. Such switchable wettability is ascribed to the modification of the alkyl and carboxylic acids groups on the laser-structured surfaces. The as-prepared surfaces have both oil-resistance and oil-collection abilities by selectively showing underwater superoleophobicity and superoleophilicity. The smart surfaces with pH-responsive oil wettability will have important applications in controlling the oil behavior in water 
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700 1 |a Yong, Jiale  |e verfasserin  |4 aut 
700 1 |a Yang, Qing  |e verfasserin  |4 aut 
700 1 |a Chen, Feng  |e verfasserin  |4 aut 
700 1 |a Hou, Xun  |e verfasserin  |4 aut 
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